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- W4382023289 abstract "The binding actions of a mixed-ligand copper complex, [Cu(bpy)(MBZ)2(H2O)] (bpy = 2, 2´-bipyridine, MBZ = p-methylbenzoate) to single-stranded (ss-) DNA and double-stranded (ds-) DNA were comprehensively studied via electrochemical methods in this paper. Cyclic and differential pulse voltammetry carried out in homogeneous solution showed that the copper complex underwent different variation after interaction with dsDNA and ssDNA, showing the different binding mechanism of the copper complex to dsDNA and ssDNA. The determination of the electron-transfer rates (Ks) suggested that the electro-activities of [Cu(bpy)(MBZ)2(H2O)]-dsDNA and [Cu(bpy)(MBZ)2(H2O)]-ssDNA complexes decreased in different extents compared with the free state of the complex. The thermodynamic binding parameters and kinetic dissociation constants of [Cu(bpy)(MBZ)2(H2O)] with dsDNA and ssDNA were also assessed by surface methods. Based on all the results, an intercalative mode of the copper complex to dsDNA and a coordination mode of the copper complex to ssDNA were proposed, which was further testified by the emission experiments." @default.
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- W4382023289 date "2011-05-01" @default.
- W4382023289 modified "2023-10-16" @default.
- W4382023289 title "Electrochemical Studies on the Recognition of a Ternary Copper Complex to Single-Stranded DNA and Double-Stranded DNA" @default.
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- W4382023289 doi "https://doi.org/10.1016/s1452-3981(23)15089-9" @default.
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