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- W4382059945 abstract "Two novel monomers 9-(4-(thiophen-2-yl)phenyl)-9H-carbazole (CBT) and 9-(4-(3-methylthiophen- 2-yl)phenyl)-9H-carbazole (CBMT) were synthesized via Suzuki coupling reaction. And, the corresponding polymers PCBT and PCBMT were synthesized electrochemically and characterized in detail. The color of the PCBT was light yellow in its neutral state, and tured to ashy color in the oxidized state, in intermediate states, mahogany color was observed. PCBMT film switches between a colorless state, a gray intermediate state, and a grayish blue oxidized state. The methyl group on the side-chain of the thienyl unites effectively tuned the optical and electronic properties of the polymers, including Eg, HOMO/LUMO, switching properties, etc. The results suggested that the influence of introducing electron-donating group(e.g. methyl group) on polymer's opto-electochemical properties must be considered from the aspects of both the electronic factor and the group's steric effect in polymers." @default.
- W4382059945 created "2023-06-27" @default.
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- W4382059945 date "2014-07-01" @default.
- W4382059945 modified "2023-09-25" @default.
- W4382059945 title "Substituent Effect on Opto-Electrochemical Properties of Thienyl-Derivatized Poly(Phenylcarbazole)S" @default.
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- W4382059945 doi "https://doi.org/10.1016/s1452-3981(23)08027-6" @default.
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