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- W4382073661 endingPage "121661" @default.
- W4382073661 startingPage "121661" @default.
- W4382073661 abstract "The structure and aromaticity of metalla-aromatics show diversity. In this work, we report the synthesis of polycyclic cyclopropaosmabenzenes, which contained an aromatic osmacyclopropene and an aromatic osmabenzene unit. The complexes were isolated from the reactions of OsCl2(PPh3)3 with enediynes E-HC≡CCH=C(SiMe3)C≡CR (R = p-tol, Ph) in the presence of PPh3 followed by the protonation with HCl. The σ-aromaticity (in osmacyclopropene unit) and the π-aromaticity (in osmabenzene unit) of the polycyclic cyclopropaosmabenzene are supported by experimental observations and theoretical calculations." @default.
- W4382073661 created "2023-06-27" @default.
- W4382073661 creator A5005062291 @default.
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- W4382073661 creator A5058079830 @default.
- W4382073661 creator A5068512326 @default.
- W4382073661 creator A5083370868 @default.
- W4382073661 date "2023-10-01" @default.
- W4382073661 modified "2023-10-17" @default.
- W4382073661 title "Synthesis and characterization of cyclopropaosmabenzenes containing a fused σ-aromatic metallacyclopropene unit" @default.
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