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- W4382140586 abstract "Vinylene carbonate (VC) has higher reduction potential than that of 1-butyl-3-methyl-imidazolium tetrafluoroborate (BMIMBF4) and can form solid electrolyte interface (SEI) film on lithium (Li) metal surface. VC modified the mixed electrolyte based on BMIMBF4 and γ -butyrolactone (γ-BL) has been investigated. The result indicates that the optimized mixed electrolyte, γ-BL / BMIMBF4 (70/30, volume ratio) -1 M LiBF4, has high conductivity(14.87 mS cm-1) at 25 °C. Electrochemical impedance spectroscopy discloses that the addition of VC improves the compatibility of the mixed electrolyte towards lithium anodes and enhances the formation of SEI film to protect lithium anodes from corrosion. Accordingly, the Li/LiFePO4 battery with VC modified the BMIMBF4/γ-BL -1 M LiBF4, has a high discharge capacity of 123.1 mAh g-1 without any considerable fading during the first 20 cycles at a current density of 0.1C." @default.
- W4382140586 created "2023-06-27" @default.
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- W4382140586 date "2012-08-01" @default.
- W4382140586 modified "2023-10-10" @default.
- W4382140586 title "Vinylene Carbonate Modified 1-Butyl-3-Methyle-Imidazolium Tetrafluoroborate Ionic Liquid Mixture as Electrolyte" @default.
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- W4382140586 doi "https://doi.org/10.1016/s1452-3981(23)15806-8" @default.
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