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• W4382182548 endingPage "14883" @default.
• W4382182548 startingPage "14874" @default.
• W4382182548 abstract "Low sensitivity is the primary limitation to extending nuclear magnetic resonance (NMR) techniques to more advanced chemical and structural studies. Photochemically induced dynamic nuclear polarization (photo-CIDNP) is an NMR hyperpolarization technique where light is used to excite a suitable donor-acceptor system, creating a spin-correlated radical pair whose evolution drives nuclear hyperpolarization. Systems that exhibit photo-CIDNP in solids are not common, and this effect has, up to now, only been observed for 13C and 15N nuclei. However, the low gyromagnetic ratio and natural abundance of these nuclei trap the local hyperpolarization in the vicinity of the chromophore and limit the utility for bulk hyperpolarization. Here, we report the first example of optically enhanced solid-state 1H NMR spectroscopy in the high-field regime. This is achieved via photo-CIDNP of a donor-chromophore-acceptor molecule in a frozen solution at 0.3 T and 85 K, where spontaneous spin diffusion among the abundant strongly coupled 1H nuclei relays polarization through the whole sample, yielding a 16-fold bulk 1H signal enhancement under continuous laser irradiation at 450 nm. These findings enable a new strategy for hyperpolarized NMR beyond the current limits of conventional microwave-driven DNP." @default.
• W4382182548 created "2023-06-28" @default.
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• W4382182548 date "2023-06-27" @default.
• W4382182548 modified "2023-10-01" @default.
• W4382182548 title "Optically Enhanced Solid-State ¹H NMR Spectroscopy" @default.
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• W4382182548 cites W1965632491 @default.
• W4382182548 cites W1967856511 @default.
• W4382182548 cites W1973736387 @default.
• W4382182548 cites W1977263087 @default.
• W4382182548 cites W1978555953 @default.
• W4382182548 cites W1980642390 @default.
• W4382182548 cites W1981422370 @default.
• W4382182548 cites W1983306529 @default.
• W4382182548 cites W1985767604 @default.
• W4382182548 cites W1988624456 @default.
• W4382182548 cites W1995482407 @default.
• W4382182548 cites W1996786931 @default.
• W4382182548 cites W1996865209 @default.
• W4382182548 cites W1998155160 @default.
• W4382182548 cites W2002391883 @default.
• W4382182548 cites W2010450284 @default.
• W4382182548 cites W2019127523 @default.
• W4382182548 cites W2022790651 @default.
• W4382182548 cites W2031248717 @default.
• W4382182548 cites W2033346699 @default.
• W4382182548 cites W2034975629 @default.
• W4382182548 cites W2037959733 @default.
• W4382182548 cites W2038509084 @default.
• W4382182548 cites W2039051903 @default.
• W4382182548 cites W2039061794 @default.
• W4382182548 cites W2041426604 @default.
• W4382182548 cites W2043883884 @default.
• W4382182548 cites W2045251597 @default.
• W4382182548 cites W2046025841 @default.
• W4382182548 cites W2046218188 @default.
• W4382182548 cites W2048295935 @default.
• W4382182548 cites W2049230001 @default.
• W4382182548 cites W2067775343 @default.
• W4382182548 cites W2068535037 @default.
• W4382182548 cites W2070780918 @default.
• W4382182548 cites W2071023363 @default.
• W4382182548 cites W2075072191 @default.
• W4382182548 cites W2075075608 @default.
• W4382182548 cites W2084507204 @default.
• W4382182548 cites W2084952031 @default.
• W4382182548 cites W2087443640 @default.
• W4382182548 cites W2088938438 @default.
• W4382182548 cites W2111769513 @default.
• W4382182548 cites W2115682140 @default.
• W4382182548 cites W2144176808 @default.
• W4382182548 cites W2145346998 @default.
• W4382182548 cites W2148141870 @default.
• W4382182548 cites W2151731536 @default.
• W4382182548 cites W2159230887 @default.
• W4382182548 cites W2170235464 @default.
• W4382182548 cites W2171963255 @default.
• W4382182548 cites W2281847788 @default.
• W4382182548 cites W2319574108 @default.
• W4382182548 cites W2328578369 @default.
• W4382182548 cites W2339300871 @default.
• W4382182548 cites W2543943606 @default.
• W4382182548 cites W2588813796 @default.
• W4382182548 cites W2592808034 @default.
• W4382182548 cites W2596908552 @default.
• W4382182548 cites W2684578039 @default.
• W4382182548 cites W2735532111 @default.
• W4382182548 cites W2738810944 @default.
• W4382182548 cites W2754363941 @default.
• W4382182548 cites W2775162681 @default.
• W4382182548 cites W2791779919 @default.
• W4382182548 cites W2803166281 @default.
• W4382182548 cites W2805793967 @default.
• W4382182548 cites W2805972805 @default.
• W4382182548 cites W2809544297 @default.
• W4382182548 cites W2894632591 @default.
• W4382182548 cites W2910131752 @default.
• W4382182548 cites W2913308169 @default.
• W4382182548 cites W2919388402 @default.
• W4382182548 cites W2943394614 @default.
• W4382182548 cites W2944554945 @default.
• W4382182548 cites W2955080078 @default.
• W4382182548 cites W2999337320 @default.

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