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• W4382247530 abstract "Abstract Mannich‐type reactions involving alkylzinc reagents have been developed using different strategies. We show that the addition of these organometallic species to sulfonyl imines occurs upon simple heating and affords Mannich products in moderate to excellent yields (14 examples, 30–99 %). Interestingly, N ‐alkyl imines were also found to be suitable partners after activation as an acyliminium by acetyl chloride (12 examples, 49–86 %) or, more originally, by TMSCl (14 examples, 26–87 %). These methods proved complementary, leading to the preparation of both N ‐protected secondary or tertiary amines and N‐unprotected secondary amines in good yields, with an increased eco‐compatibility, and under simple conditions." @default.
• W4382247530 created "2023-06-28" @default.
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• W4382247530 date "2023-07-20" @default.
• W4382247530 modified "2023-09-30" @default.
• W4382247530 title "Mannich‐Type Reactions of Alkylzinc Reagents" @default.
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• W4382247530 doi "https://doi.org/10.1002/ejoc.202300572" @default.
• W4382247530 hasPublicationYear "2023" @default.
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