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- W4382282582 abstract "ZIF-8, a metal-organic framework, has large sorption capacities for a series of heavy metals. However, it is difficult to be separated from aqueous solution, limiting its practical application in wastewater treatment. Herein, ZIF-8 was in-situ grown on the polyethyleneimine-functionalized alginate to construct the [email protected] aerogels with a three-dimensional network structure. This synthesis strategy not only overcomes the above-mentioned defects of ZIF-8, but also provides more functional groups, pores, and channels. The synthesized [email protected] aerogels exhibit outstanding removal performance towards Pb(II) and Cd(II) with maximum sorption capacity values of 295.986 and 249.838 mg·g-1, respectively. The sorption of Pb(II) and Cd(II) on [email protected] is strongly affected by pH, but little influenced by ionic strength. In the multi-component sorption systems, [email protected] shows better sorption affinity and selectivity for Pb(II) than for Cd(II). The three-dimensional network structure constructed by alginate makes Pb(II) and Cd(II) easier to contact with the surfaces of [email protected] The strong surface complexation of the O- and N-containing functional groups provided by ZIF-8 and PEI with Pb(II) and Cd(II) makes the largest contribution to the removal of Pb(II) and Cd(II) by [email protected] In summary, the experimental findings of this work prove that the synthesized [email protected] aerogels have promising applications in practical wastewater treatment." @default.
- W4382282582 created "2023-06-28" @default.
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- W4382282582 date "2023-10-01" @default.
- W4382282582 modified "2023-10-10" @default.
- W4382282582 title "Fabrication of novel 3D PEI-functionalized ZIF-8@alginate aerogel composites for efficient elimination of Pb(II) and Cd(II) from aqueous solution" @default.
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- W4382282582 doi "https://doi.org/10.1016/j.jece.2023.110446" @default.
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