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• W4382318488 startingPage "5704" @default.
• W4382318488 abstract "Platinum cation complexes with multiple acetylene molecules are studied with mass spectrometry and infrared laser spectroscopy. Complexes of the form Pt+(C2H2)n are produced in a molecular beam by laser vaporization, analyzed with a time-of-flight mass spectrometer, and selected by mass for studies of their vibrational spectroscopy. Photodissociation action spectra in the C-H stretching region are compared to the spectra predicted for different structural isomers using density functional theory. The comparison between experiment and theory demonstrates that platinum forms cation-π complexes with up to three acetylene molecules, producing an unanticipated asymmetric structure for the three-ligand complex. Additional acetylenes form solvation structures around this three-ligand core. Reacted structures that couple acetylene molecules (e.g., to form benzene) are found by theory to be energetically favorable, but their formation is inhibited under the conditions of these experiments by large activation barriers." @default.
• W4382318488 created "2023-06-28" @default.
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• W4382318488 date "2023-06-27" @default.
• W4382318488 modified "2023-09-26" @default.
• W4382318488 title "Pt⁺(C₂H₂)_<i>n</i> Complexes Studied with Selected-Ion Infrared Spectroscopy" @default.
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• W4382318488 doi "https://doi.org/10.1021/acs.jpca.3c02734" @default.
• W4382318488 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37369010" @default.
• W4382318488 hasPublicationYear "2023" @default.
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