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- W4382393868 abstract "In this paper, a non-noble metal catalyst based on ferric chloride and melamine is synthesized via pyrolyzing in an inert atmosphere at 900 °C. The existence of Fe is demonstrated by X-ray diffraction analysis. The microstructure of the nitrogen containing carbon is investigated by the transmission electron microscopy. The bonding configurations of the surface nitrogen atoms are determined by X- ray photoelectron spectroscopy technique. The steady-state electrocatalysis for oxygen reduction is studied by the rotating disk electrode tests. We find that the nitrogen atoms in the carbon network are dominantly in the form of pyridinic nitrogen. The catalyst displays excellent performance evidenced by a high onset potential of 0.88 V for oxygen reduction reaction. As for the practical application in H2-O2 fuel cell, a power density as high as 418.20 mW cm-2 is achieved at 1100 mA cm-2 (at 25 °C) without humidification. These results imply the potential application of melamine as a nitrogen precursor in Fe based catalysts for oxygen reduction reaction." @default.
- W4382393868 created "2023-06-29" @default.
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- W4382393868 date "2012-11-01" @default.
- W4382393868 modified "2023-10-16" @default.
- W4382393868 title "Synthesis of a Novel Catalyst via Pyrolyzing Melamine with Fe Precursor and Its Excellent Electrocatalysis for Oxygen Reduction" @default.
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- W4382393868 doi "https://doi.org/10.1016/s1452-3981(23)16910-0" @default.
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