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- W4382393959 abstract "In the medium of HAc-NaAc ( pH 4.0 )， Sn ( II ) reacts with HPMHP(1-phenyl-3-methyl-4- heptanoyl -pyrazalone-5) to form a complex and there is a sharp and sensitive polarographic wave at – 0.66V(vs SCE). The peak height is linear with the concentration of Sn (II) in the range of 0.002~ 10μg·L-1 Many electrochemical methods were used to study the properties of the polargraphic wave and the mechanism of electrode reaction and it was proved that the polargraphic wave at –0.66V is an adsorptive wave of the complex. The peak current is produced by reduction of the ion Sn(II).The molar ration of the complex is Sn (II): HPMHP =1:2,and the conditional formation constant was found to be 4.05×107." @default.
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- W4382393959 date "2012-11-01" @default.
- W4382393959 modified "2023-09-25" @default.
- W4382393959 title "Electrochemical Study on Adsorptive Wave of Tin-PMHP Complex" @default.
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- W4382393959 doi "https://doi.org/10.1016/s1452-3981(23)16967-7" @default.
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