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- W4382394259 abstract "The electrode reaction of the Yb(III)/Yb(II) redox couple at W electrodes in the LiCl-KCl eutectic solutions has been studied using linear sweep voltammetry (LSV) and digital simulation method. In this work, the formal potential (E°’), standard rate constant (k°) and transfer coefficient (α) of the Yb(III)/Yb(II) redox system have been determined by a simultaneous curve fitting analysis for a series of LSV curves which were recorded in various scan rates. The regression analysis results showed that the electrode reaction (Yb3+ + e- → Yb2+) is quasi-reversible process. The formal potential, transfer coefficient and standard rate constant for the Yb(III)/Yb(II) redox reaction at W electrodes were −0.49 V vs. Ag/Ag+, 0.61, 2.7×10-2 cm/s, respectively." @default.
- W4382394259 created "2023-06-29" @default.
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- W4382394259 date "2013-05-01" @default.
- W4382394259 modified "2023-09-23" @default.
- W4382394259 title "Electrochemical Reaction of Yb(III)/Yb(II) at Tungsten Electrodes in LiCl-KCl Eutectic Melts" @default.
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- W4382394259 doi "https://doi.org/10.1016/s1452-3981(23)14805-x" @default.
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