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- W4382397510 abstract "In this study, the effect of various produce conditions on the construction and general performance of a novel modified carbon paste electrode for the determination of diazepam was discussed. Diazepam - tetraphenylborate (DZP-TPB) ion pairs have been prepared and used as electro active materials. The electrode shows a stable, potentiometric response for diazepam in the concentration range 1×10-2 - 5×10-5 M at 25 °C independent of pH in the range 3 - 5. The electrode passed near Nernstian cationic slope of 58.6±0.2 mV and lower detection limit of 8×10-7 M with a fast response time of 5-10s. Selectivity coefficients for diazepam relative to a number of interfering substances have been investigated. There is a negligible interference from the studied cations. These results have been obtained using the proposed electrodes by using a (HPLC) reference method showed that the ion- selective electrode technique is sensitive, reliable and can be used with very good accuracy and high % recovery without pretreatment procedures of the samples to minimize interfering matrix effects." @default.
- W4382397510 created "2023-06-29" @default.
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- W4382397510 date "2014-12-01" @default.
- W4382397510 modified "2023-10-09" @default.
- W4382397510 title "Preparation of Unique Potentiometric Carbon Paste Sensor for Determination of Diazepam in Pharmaceutical applications" @default.
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- W4382397510 doi "https://doi.org/10.1016/s1452-3981(23)10988-6" @default.
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