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- W4382397568 abstract "In this work, nanographene was used as a proper nano-material to modify the composition of carbon paste electrode. Because of a selective interaction between 4-methyl-1,2-bis(2-pyridinecarboxamido) benzene (MPB) and thulium ions identified by our previous work, MPB was incorporated as a sensing material into a nano-composite carbon paste electrodes. The paste is composed of graphite, sensing material MPB, nanographene (NG), and a room temperature ionic liquid namely 1-n-butyl-3-methylimidazolium tetrafluoroborate [bmim]BF4 (RTIL). The electrodes made of 50% graphite, 5% NG, 20% MPB, and 25% RTIL were found to show the most favorable behavior. The sensor shows a Nernstian response (19.9±0.3 mV decade-1) in the concentration window of 1.0×10-6-1.0×10-2 M with detection limit of 8.3×10-7 M. The response of the sensor was found to be stable in the pH range of 3.5-9.0 and the nano-composite based Tm(III) sensors displayed very good selectivity with respect to a number of lanthanide and transition metal ions. The proposed sensor displays a long life time (more than 12 weeks) with a short response time of about 15 s." @default.
- W4382397568 created "2023-06-29" @default.
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- W4382397568 date "2011-08-01" @default.
- W4382397568 modified "2023-10-16" @default.
- W4382397568 title "Thulium Selective Sensor based on Nanographene/RTIL/Ionophore/Graphite" @default.
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- W4382397568 doi "https://doi.org/10.1016/s1452-3981(23)18280-0" @default.
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