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• W4382582011 abstract "Nanoporous copper (NPC) ribbons with hybrid-modal pore size distributions can be facilely fabricated by effectively controlling the surface diffusivity of Cu atoms during chemical dealloying of dual-phase Mg 13.5 at.% Cu alloy with quasieutectic structures in the HCl solution. These NPC ribbons can be featured by a combination of ligament-pore structures with unimodal pore size distributions at superficial layers and those with bimodal pore size distributions in the interior composed of interconnected large-sized pores with highly porous pore walls. All pores in the ligament-pore structures with unimodal and bimodal pore size distributions are 3D, open and bicontinuous. The formation of the novel NPC ribbons can be well explained as a consequence of the greater diffusivity of Cu atoms at the superficial layers induced by the higher absorbed Cl- concentration. According to the ligament sizes, the surface diffusivity of Cu atoms at the superficial layers can be evaluated as 1.68×10-16 m2 s-1, which is two orders of magnitude greater than that in the interior of the NPC ribbons (3.55×10-19 m2 s-1)." @default.
• W4382582011 created "2023-06-30" @default.
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• W4382582011 date "2012-01-01" @default.
• W4382582011 modified "2023-09-30" @default.
• W4382582011 title "Formation of Nanoporous Copper with Hybrid-Modal Pore Size Distributions Related to Surface Diffusion of Copper Atoms During Dealloying of Mg 13.5 at.% Cu Alloy in an Acidic Solution" @default.
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• W4382582011 doi "https://doi.org/10.1016/s1452-3981(23)19487-9" @default.
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