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- W4382584078 abstract "Screen-printed electrode (SPE) was constructed for the determination of N-(1,1,2,2- tetrahydroperfluorooctyl)-N,N-dimethylammonium chloride (TFACl) surfactant and its electrochemical response characteristics were described. The fabricated electrode was based on the use of ion-associate formed between TFACl and sodium dodecylsulphate (SDS) as exchange sites in screen-printed electrode in the presence of tricresylphosphate (TCP) as a solvent mediator. The electrode has Nernstian cationic slope of 58.34±0.52 mV decade-1 with a linear concentration range from 1.0×10-2 to 8.2×10-7 mol L-1. The electrode has a lower limit of detection of 8.2×10-7 mol L-1 and response time of about 10s. It exhibits adequate shelf-life of 160 days and has a constant potential over the pH range of 2.0 - 8.5. The obtained selectivity coefficient values indicate better selectivity for TFACl over many common monovalent or divalent cations as well as dodecyltrimethylammonium bromide (DTAB) surfactant. The analytical application of the SPE sensor was successfully tested by potentiometric titration of a TFACl solution with SDS in pure and some water samples. The analytical and technical grade TFACl used in this study as well as different spiked water samples was determined successfully using the proposed direct potentiometric methods. The data obtained have good agreement with those obtained on applying standard two phase titration method. The results obtained applying the proposed potentiometric method are comparable with the official method indicating its possibility to be applied in field measurements." @default.
- W4382584078 created "2023-06-30" @default.
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- W4382584078 date "2016-01-01" @default.
- W4382584078 modified "2023-10-14" @default.
- W4382584078 title "Electrochemical Determination of N-(1,1,2,2- tetrahydroperfluorooctyl)-N,N-dimethylammonium Chloride Surfactant in Different Water Samples Using Modified Screen- Printed Electrode" @default.
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- W4382584078 doi "https://doi.org/10.1016/s1452-3981(23)15904-9" @default.
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