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• W4382584871 abstract "Mn-doped LiFePO4/C cathode materials were synthesized by a carbothermal reduction technique using sucrose as both the reduction agent and the carbon source. The microstructure and electrochemical performance were systematically investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), Raman spectroscopy, charge-discharge cycling, cyclic voltammograms and electrochemical impedance spectroscopy. It is found that the all as-prepared composites have a single phase of orthorhombic olivine-type structure and Mn2+ has successfully introduced into the M2(Fe) sites. Among the as-prepared comosites, LiFe0.98Mn0.02PO4/C demonstrates a best electrochemical property in terms of discharge capacity, electrochemical reversibility and cycling performance with an initial discharge capacity of 165 mAh·g-1 at a discharge rate of 0.2C. The improved electrochemical performance should be attributed to the smaller particle, the enhancement of the P-O bond and the facilitation of Li+ ion “effective” diffusion induced by Mn2+-substitution." @default.
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• W4382584871 date "2011-12-01" @default.
• W4382584871 modified "2023-10-15" @default.
• W4382584871 title "An optimized Mn-doped LiFePO4/C Composite Synthesized by Carbonthermal Reduction Technique" @default.
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• W4382584871 doi "https://doi.org/10.1016/s1452-3981(23)19709-4" @default.
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