Matches in SemOpenAlex for { <https://semopenalex.org/work/W4382722017> ?p ?o ?g. }
- W4382722017 endingPage "18853" @default.
- W4382722017 startingPage "18844" @default.
- W4382722017 abstract "Laser-induced reduction of metal ions is attracting increasing attention as a sustainable route to ligand-free metal nanoparticles. In this work, we investigate the photochemical reactions involved in reduction of Ag+ and [AuCl4]- upon interaction with lasers with nanosecond and femtosecond pulse duration, using strong-field ionization mass spectrometry and spectroscopic assays to identify stable molecular byproducts. Whereas Ag+ in aqueous isopropyl alcohol (IPA) is reduced through plasma-mediated mechanisms upon femtosecond laser excitation, low-fluence nanosecond laser excitation induces electron transfer from IPA to Ag+. Both nanosecond and femtosecond laser excitation of aqueous [AuCl4]- produce reactive chlorine species by Au-Cl bond homolysis. Formation of numerous volatile products by IPA decomposition during both femtosecond and nanosecond laser excitation of [AuCl4]- is attributed to enhanced optical breakdown by the Au nanoparticle products of [AuCl4]- reduction. These mechanistic insights can inform the design of laser synthesis procedures to improve control over metal nanoparticle properties and enhance byproduct yields." @default.
- W4382722017 created "2023-07-01" @default.
- W4382722017 creator A5027202120 @default.
- W4382722017 creator A5059625211 @default.
- W4382722017 creator A5076970883 @default.
- W4382722017 creator A5080261255 @default.
- W4382722017 creator A5092370091 @default.
- W4382722017 creator A5092370092 @default.
- W4382722017 creator A5092370093 @default.
- W4382722017 date "2023-01-01" @default.
- W4382722017 modified "2023-09-27" @default.
- W4382722017 title "Understanding photochemical pathways of laser-induced metal ion reduction through byproduct analysis" @default.
- W4382722017 cites W1965268444 @default.
- W4382722017 cites W1968187667 @default.
- W4382722017 cites W1976439152 @default.
- W4382722017 cites W1981010287 @default.
- W4382722017 cites W1991297974 @default.
- W4382722017 cites W1997903375 @default.
- W4382722017 cites W2003598751 @default.
- W4382722017 cites W2008846993 @default.
- W4382722017 cites W2013172671 @default.
- W4382722017 cites W2017719233 @default.
- W4382722017 cites W2017955796 @default.
- W4382722017 cites W2019521943 @default.
- W4382722017 cites W2019704742 @default.
- W4382722017 cites W2048917812 @default.
- W4382722017 cites W2050486159 @default.
- W4382722017 cites W2061885508 @default.
- W4382722017 cites W2067731923 @default.
- W4382722017 cites W2078128999 @default.
- W4382722017 cites W2092284751 @default.
- W4382722017 cites W2093483749 @default.
- W4382722017 cites W2106589142 @default.
- W4382722017 cites W2152342099 @default.
- W4382722017 cites W2159229647 @default.
- W4382722017 cites W2170337401 @default.
- W4382722017 cites W2206289531 @default.
- W4382722017 cites W2315285187 @default.
- W4382722017 cites W2322861955 @default.
- W4382722017 cites W2329007701 @default.
- W4382722017 cites W2334163178 @default.
- W4382722017 cites W2347014697 @default.
- W4382722017 cites W2586681018 @default.
- W4382722017 cites W2588342129 @default.
- W4382722017 cites W2604678920 @default.
- W4382722017 cites W2606364542 @default.
- W4382722017 cites W2606536159 @default.
- W4382722017 cites W2623543992 @default.
- W4382722017 cites W2747355282 @default.
- W4382722017 cites W2766132967 @default.
- W4382722017 cites W2793648817 @default.
- W4382722017 cites W2888347597 @default.
- W4382722017 cites W2899010195 @default.
- W4382722017 cites W2911942666 @default.
- W4382722017 cites W2937200557 @default.
- W4382722017 cites W2964621826 @default.
- W4382722017 cites W2965575303 @default.
- W4382722017 cites W3043839353 @default.
- W4382722017 cites W3049652315 @default.
- W4382722017 cites W3121100038 @default.
- W4382722017 cites W3137642042 @default.
- W4382722017 cites W3157831785 @default.
- W4382722017 cites W3184118031 @default.
- W4382722017 cites W4247550378 @default.
- W4382722017 cites W4281790829 @default.
- W4382722017 cites W4296698870 @default.
- W4382722017 cites W4307046008 @default.
- W4382722017 cites W771400008 @default.
- W4382722017 doi "https://doi.org/10.1039/d3cp00052d" @default.
- W4382722017 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37403595" @default.
- W4382722017 hasPublicationYear "2023" @default.
- W4382722017 type Work @default.
- W4382722017 citedByCount "0" @default.
- W4382722017 crossrefType "journal-article" @default.
- W4382722017 hasAuthorship W4382722017A5027202120 @default.
- W4382722017 hasAuthorship W4382722017A5059625211 @default.
- W4382722017 hasAuthorship W4382722017A5076970883 @default.
- W4382722017 hasAuthorship W4382722017A5080261255 @default.
- W4382722017 hasAuthorship W4382722017A5092370091 @default.
- W4382722017 hasAuthorship W4382722017A5092370092 @default.
- W4382722017 hasAuthorship W4382722017A5092370093 @default.
- W4382722017 hasBestOaLocation W43827220171 @default.
- W4382722017 hasConcept C119599485 @default.
- W4382722017 hasConcept C120665830 @default.
- W4382722017 hasConcept C121332964 @default.
- W4382722017 hasConcept C127413603 @default.
- W4382722017 hasConcept C145148216 @default.
- W4382722017 hasConcept C167735695 @default.
- W4382722017 hasConcept C178790620 @default.
- W4382722017 hasConcept C185592680 @default.
- W4382722017 hasConcept C192562407 @default.
- W4382722017 hasConcept C22078206 @default.
- W4382722017 hasConcept C51141536 @default.
- W4382722017 hasConcept C520434653 @default.
- W4382722017 hasConcept C75473681 @default.
- W4382722017 hasConcept C83581075 @default.
- W4382722017 hasConceptScore W4382722017C119599485 @default.
- W4382722017 hasConceptScore W4382722017C120665830 @default.