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- W4382931342 abstract "Comprehensive Summary Axially chiral N ‐arylindoles bearing a stereogenic C—N axis are unique important scaffolds in natural products, advance materials, pharmaceuticals and privileged chiral ligands or catalysts. Herein, we report the direct synthesis of C—N axially chiral N ‐arylindoles through a Pd‐catalyzed free amine‐directed atroposelective C—H olefination enabled by a spiro phosphoric acid (SPA) ligand. A wide range of enantioenriched N ‐aromatic amine indoles were obtained in high yields with good enantioselectivities (35 examples, up to 91% yield and up to 96% ee). The chiral products with free amine group offer an effective functional handle for down‐stream diversity‐oriented synthesis." @default.
- W4382931342 created "2023-07-04" @default.
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- W4382931342 date "2023-07-25" @default.
- W4382931342 modified "2023-10-17" @default.
- W4382931342 title "Synthesis of C—N Axial Chirality <scp><i>N</i>‐Arylindoles</scp> via Pd(<scp>II</scp>)‐Catalyzed Free <scp>Amine‐Directed</scp> Atroposelective C—H Olefination<sup>†</sup>" @default.
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- W4382931342 doi "https://doi.org/10.1002/cjoc.202300355" @default.
- W4382931342 hasPublicationYear "2023" @default.
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