Matches in SemOpenAlex for { <https://semopenalex.org/work/W4382931703> ?p ?o ?g. }
- W4382931703 abstract "An isomorphous series of coordination polymers with the general formula M(H2O)4[Pd(iso-maleonitriledithiolate)2]·2H2O (M = Mn, Co, Zn) was structurally characterized. They exhibit a 1-D zig-zag chain structure which further interacts via hydrogen bonding to form a highly aligned 2-D array of 1-D chains in the solid state. Single crystals are moderately pigmented orange in color when viewed under unpolarized visible light, but under plane-polarized light, they are dichroic down the 001 face, with a change in color from red to yellow upon rotation by 90°. Solid-state polarized absorption and, for the Zn-analogue, unpolarized emission spectra are reported and assigned as an MLCT transition and a d–d transition involving an excited triplet state with the LUMO (dx2-y2) populated by one electron, respectively. These materials represent the first transition-metal coordination polymers that incorporate the [Pd(i-mnt)2]2– building block." @default.
- W4382931703 created "2023-07-04" @default.
- W4382931703 creator A5035673972 @default.
- W4382931703 creator A5060415217 @default.
- W4382931703 creator A5083168740 @default.
- W4382931703 creator A5084578768 @default.
- W4382931703 creator A5085358227 @default.
- W4382931703 date "2023-07-03" @default.
- W4382931703 modified "2023-09-30" @default.
- W4382931703 title "Dichroic Palladium Dithiolate Coordination Polymers" @default.
- W4382931703 cites W140032059 @default.
- W4382931703 cites W1532095700 @default.
- W4382931703 cites W169845824 @default.
- W4382931703 cites W1739703038 @default.
- W4382931703 cites W1962522742 @default.
- W4382931703 cites W1963919797 @default.
- W4382931703 cites W1969360633 @default.
- W4382931703 cites W1974836802 @default.
- W4382931703 cites W1976639656 @default.
- W4382931703 cites W1976920410 @default.
- W4382931703 cites W1977189822 @default.
- W4382931703 cites W1983935783 @default.
- W4382931703 cites W1990687771 @default.
- W4382931703 cites W1991821172 @default.
- W4382931703 cites W1992973838 @default.
- W4382931703 cites W1998515676 @default.
- W4382931703 cites W2004317657 @default.
- W4382931703 cites W2004627268 @default.
- W4382931703 cites W2004842014 @default.
- W4382931703 cites W2015972185 @default.
- W4382931703 cites W2021010845 @default.
- W4382931703 cites W2027889879 @default.
- W4382931703 cites W2030841140 @default.
- W4382931703 cites W2031560148 @default.
- W4382931703 cites W2033326741 @default.
- W4382931703 cites W2034460753 @default.
- W4382931703 cites W2039952987 @default.
- W4382931703 cites W2046193699 @default.
- W4382931703 cites W2046361778 @default.
- W4382931703 cites W2049297611 @default.
- W4382931703 cites W2051565418 @default.
- W4382931703 cites W2051650270 @default.
- W4382931703 cites W2055170848 @default.
- W4382931703 cites W2059205366 @default.
- W4382931703 cites W2060048911 @default.
- W4382931703 cites W2066870658 @default.
- W4382931703 cites W2070059498 @default.
- W4382931703 cites W2075650720 @default.
- W4382931703 cites W2081112147 @default.
- W4382931703 cites W2083395925 @default.
- W4382931703 cites W2083495335 @default.
- W4382931703 cites W2086910210 @default.
- W4382931703 cites W2090084145 @default.
- W4382931703 cites W2091839980 @default.
- W4382931703 cites W2103382383 @default.
- W4382931703 cites W2137173046 @default.
- W4382931703 cites W2145991075 @default.
- W4382931703 cites W2157112978 @default.
- W4382931703 cites W2164647291 @default.
- W4382931703 cites W2224046307 @default.
- W4382931703 cites W2225667184 @default.
- W4382931703 cites W2275780265 @default.
- W4382931703 cites W2317553436 @default.
- W4382931703 cites W2327596617 @default.
- W4382931703 cites W2329698603 @default.
- W4382931703 cites W2331594899 @default.
- W4382931703 cites W2332589679 @default.
- W4382931703 cites W2339415144 @default.
- W4382931703 cites W2417114816 @default.
- W4382931703 cites W2588526347 @default.
- W4382931703 cites W2611118737 @default.
- W4382931703 cites W2950872118 @default.
- W4382931703 cites W3097089333 @default.
- W4382931703 cites W3116953340 @default.
- W4382931703 cites W3128963167 @default.
- W4382931703 cites W3157837248 @default.
- W4382931703 cites W4220774789 @default.
- W4382931703 cites W4249970733 @default.
- W4382931703 doi "https://doi.org/10.1021/acs.cgd.3c00428" @default.
- W4382931703 hasPublicationYear "2023" @default.
- W4382931703 type Work @default.
- W4382931703 citedByCount "0" @default.
- W4382931703 crossrefType "journal-article" @default.
- W4382931703 hasAuthorship W4382931703A5035673972 @default.
- W4382931703 hasAuthorship W4382931703A5060415217 @default.
- W4382931703 hasAuthorship W4382931703A5083168740 @default.
- W4382931703 hasAuthorship W4382931703A5084578768 @default.
- W4382931703 hasAuthorship W4382931703A5085358227 @default.
- W4382931703 hasConcept C104663316 @default.
- W4382931703 hasConcept C106773901 @default.
- W4382931703 hasConcept C107814960 @default.
- W4382931703 hasConcept C115624301 @default.
- W4382931703 hasConcept C121332964 @default.
- W4382931703 hasConcept C147789679 @default.
- W4382931703 hasConcept C161790260 @default.
- W4382931703 hasConcept C171250308 @default.
- W4382931703 hasConcept C178790620 @default.
- W4382931703 hasConcept C181500209 @default.
- W4382931703 hasConcept C184779094 @default.
- W4382931703 hasConcept C185592680 @default.