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- W4382983146 endingPage "107258" @default.
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- W4382983146 abstract "Unanticipated formation of symmetrical sulfonyl guanidine was observed while treating isonitriles with N,N-dibromoarylsulfonamides in absence of an external amine source. Interesting feature of this work is that one molecule of isonitrile initially reacts with dibromoarylsulfonamide via the C-end to produce the intermediate carbodiimide while the other molecule undergoes C≡N triple bond cleavage to react as amine source with the intermediate. This switch of reactivity from C-center to N-center of the isonitrile generated symmetrical guanidine." @default.
- W4382983146 created "2023-07-04" @default.
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- W4382983146 date "2023-08-01" @default.
- W4382983146 modified "2023-10-14" @default.
- W4382983146 title "Unanticipated switch of reactivity of isonitrile via N≡C bond scission: Cascade formation of symmetrical sulfonyl guanidine" @default.
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- W4382983146 doi "https://doi.org/10.1016/j.isci.2023.107258" @default.
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