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- W4382988424 abstract "Conventional solid-to-solid conversion-type cathodes in batteries suffer from poor diffusion/reaction kinetics, large volume changes and aggressive structural degradation, particularly for rechargeable aluminium batteries (RABs). Here we report a class of high-capacity redox couples featuring a solution-to-solid conversion chemistry with well-manipulated solubility as cathodes-uniquely allowed by using molten salt electrolytes-that enable fast-charging and long-lived RABs. As a proof-of-concept, we demonstrate a highly reversible redox couple-the highly soluble InCl and the sparingly soluble InCl3-that exhibits a high capacity of about 327 mAh g-1 with negligible cell overpotential of only 35 mV at 1 C rate and 150 °C. The cells show almost no capacity fade over 500 cycles at a 20 C charging rate and can sustain 100 mAh g-1 at 50 C. The fast oxidation kinetics of the solution phase upon initiating the charge enables the cell with ultrafast charging capability, whereas the structure self-healing via re-forming the solution phase at the end of discharge endows the long-term cycling stability. This solution-to-solid mechanism will unlock more multivalent battery cathodes that are attractive in cost but plagued by poor reaction kinetics and short cycle life." @default.
- W4382988424 created "2023-07-04" @default.
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- W4382988424 date "2023-07-03" @default.
- W4382988424 modified "2023-10-06" @default.
- W4382988424 title "A solution-to-solid conversion chemistry enables ultrafast-charging and long-lived molten salt aluminium batteries" @default.
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- W4382988424 doi "https://doi.org/10.1038/s41467-023-39258-y" @default.
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