Matches in SemOpenAlex for { <https://semopenalex.org/work/W4383041489> ?p ?o ?g. }
- W4383041489 endingPage "107910" @default.
- W4383041489 startingPage "107910" @default.
- W4383041489 abstract "Seven typical lignin monomers with different number of methoxyl groups and different 4-substituted patterns were pyrolyzed at 500 °C and 700 °C for 120 s to simulate the secondary polymerization and side chain conversion reactions of primary pyrolytic lignin monomers. The pyrolytic heavy oil components were identified at molecular scale with Fourier transform-ion cyclotron resonance mass spectrometry (FT-ICR-MS) and analyzed with Kendrick mass defect (KMD) and van Krevelen diagrams. The detected heavy components were typically phenolic oligomers formed dominantly through the radical coupling reactions of phenol radicals (C6H4O) and methoxyl radicals (OCH2). Model compounds with CC type 4-substituted groups were prone to produce more phenolic oligomers with more aromatic units. For the CO type model compounds, the number of methoxyl groups have significant influence on the generation of heavy components, thereby affecting the char yields. Rising temperature promotes the generation of heavy components through three main routes, namely the additions of CH2, OCH2 and C6H4O. These routes were mapped on van Krevelen diagrams, shedding light on the evolution patterns of both polymerization and side chain conversion reactions during the secondary pyrolysis of lignin." @default.
- W4383041489 created "2023-07-04" @default.
- W4383041489 creator A5006030045 @default.
- W4383041489 creator A5007450053 @default.
- W4383041489 creator A5024934519 @default.
- W4383041489 creator A5027835055 @default.
- W4383041489 creator A5036963612 @default.
- W4383041489 creator A5071530078 @default.
- W4383041489 date "2023-11-01" @default.
- W4383041489 modified "2023-10-14" @default.
- W4383041489 title "Evolution of lignin pyrolysis heavy components through the study of representative lignin monomers" @default.
- W4383041489 cites W1963761986 @default.
- W4383041489 cites W1971144082 @default.
- W4383041489 cites W1976302507 @default.
- W4383041489 cites W1978473552 @default.
- W4383041489 cites W2011032908 @default.
- W4383041489 cites W2011781230 @default.
- W4383041489 cites W2017368391 @default.
- W4383041489 cites W2019876160 @default.
- W4383041489 cites W2043557587 @default.
- W4383041489 cites W2052366584 @default.
- W4383041489 cites W2074704891 @default.
- W4383041489 cites W2103423361 @default.
- W4383041489 cites W2112851854 @default.
- W4383041489 cites W2129707217 @default.
- W4383041489 cites W2149902591 @default.
- W4383041489 cites W2208313037 @default.
- W4383041489 cites W2278233382 @default.
- W4383041489 cites W2305278382 @default.
- W4383041489 cites W2374229039 @default.
- W4383041489 cites W2397442616 @default.
- W4383041489 cites W2412888405 @default.
- W4383041489 cites W2513124593 @default.
- W4383041489 cites W2519224541 @default.
- W4383041489 cites W2575536271 @default.
- W4383041489 cites W2781898095 @default.
- W4383041489 cites W2782590469 @default.
- W4383041489 cites W2783757378 @default.
- W4383041489 cites W2796122189 @default.
- W4383041489 cites W2887156629 @default.
- W4383041489 cites W2891981828 @default.
- W4383041489 cites W2899935167 @default.
- W4383041489 cites W2923078072 @default.
- W4383041489 cites W2999860974 @default.
- W4383041489 cites W3011589534 @default.
- W4383041489 cites W3037080812 @default.
- W4383041489 cites W3037485837 @default.
- W4383041489 cites W3117078744 @default.
- W4383041489 cites W3157341555 @default.
- W4383041489 cites W3186109532 @default.
- W4383041489 cites W3195466003 @default.
- W4383041489 cites W3197259676 @default.
- W4383041489 cites W3207270058 @default.
- W4383041489 cites W4200589161 @default.
- W4383041489 cites W4206277937 @default.
- W4383041489 cites W4206766420 @default.
- W4383041489 cites W4225151873 @default.
- W4383041489 cites W4288032444 @default.
- W4383041489 cites W4308157447 @default.
- W4383041489 doi "https://doi.org/10.1016/j.fuproc.2023.107910" @default.
- W4383041489 hasPublicationYear "2023" @default.
- W4383041489 type Work @default.
- W4383041489 citedByCount "0" @default.
- W4383041489 crossrefType "journal-article" @default.
- W4383041489 hasAuthorship W4383041489A5006030045 @default.
- W4383041489 hasAuthorship W4383041489A5007450053 @default.
- W4383041489 hasAuthorship W4383041489A5024934519 @default.
- W4383041489 hasAuthorship W4383041489A5027835055 @default.
- W4383041489 hasAuthorship W4383041489A5036963612 @default.
- W4383041489 hasAuthorship W4383041489A5071530078 @default.
- W4383041489 hasConcept C139066938 @default.
- W4383041489 hasConcept C145148216 @default.
- W4383041489 hasConcept C166940927 @default.
- W4383041489 hasConcept C170552419 @default.
- W4383041489 hasConcept C178790620 @default.
- W4383041489 hasConcept C185592680 @default.
- W4383041489 hasConcept C188027245 @default.
- W4383041489 hasConcept C2777702071 @default.
- W4383041489 hasConcept C2779970684 @default.
- W4383041489 hasConcept C2781052789 @default.
- W4383041489 hasConcept C36759035 @default.
- W4383041489 hasConcept C44228677 @default.
- W4383041489 hasConcept C521977710 @default.
- W4383041489 hasConcept C6775980 @default.
- W4383041489 hasConceptScore W4383041489C139066938 @default.
- W4383041489 hasConceptScore W4383041489C145148216 @default.
- W4383041489 hasConceptScore W4383041489C166940927 @default.
- W4383041489 hasConceptScore W4383041489C170552419 @default.
- W4383041489 hasConceptScore W4383041489C178790620 @default.
- W4383041489 hasConceptScore W4383041489C185592680 @default.
- W4383041489 hasConceptScore W4383041489C188027245 @default.
- W4383041489 hasConceptScore W4383041489C2777702071 @default.
- W4383041489 hasConceptScore W4383041489C2779970684 @default.
- W4383041489 hasConceptScore W4383041489C2781052789 @default.
- W4383041489 hasConceptScore W4383041489C36759035 @default.
- W4383041489 hasConceptScore W4383041489C44228677 @default.
- W4383041489 hasConceptScore W4383041489C521977710 @default.
- W4383041489 hasConceptScore W4383041489C6775980 @default.