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• W4383105066 startingPage "171216" @default.
• W4383105066 abstract "Bisphenol A (BPA), an endocrine disrupting chemical, had been used worldwide as a raw material in water bottles and food packages. It leaches into food products and water sources and hence, it should be monitored effectively. Herein, an electrochemical sensing platform based on [email protected] modified glassy carbon (GC) electrode was fabricated for the sensing of BPA. The material was synthesized by a simple solvothermal method, carbonized at 500 ⁰C, and characterized by various surface analytical techniques. Cyclic voltammetric (CV) analysis reveals that the [email protected] modified GCE exhibits 1.5 folds hike in peak current and a considerable shift in peak potential towards the anodic side when compared to [email protected], suggesting the higher electrocatalytic activity of the former than that of the later. The electrochemical oxidation of BPA provides an irreversible diffusion-controlled process involving two electrons and two protons. Differential pulse voltammetric (DPV) analysis reveals that the constructed sensor material provides a linear response over BPA concentration of 1−150 µM with a low detection limit (LOD) of 0.06 µM, (S/N=3) and amperometric studies deliver a linear range of 1-22 µM with a LOD of 0.025 µM in 0.1 M PBS at a pH 7.0. Additionally, the [email protected] delivers good repeatability, stability, and anti-interference capabilities. The results obtained also support the effectiveness of [email protected] for quantifying and identifying BPA in real sample analysis (plastic water bottles) with an average recovery of the ratio of 101.93 having a relative standard deviation (RSD) of 0.42%." @default.
• W4383105066 created "2023-07-05" @default.
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• W4383105066 date "2023-11-01" @default.
• W4383105066 modified "2023-10-16" @default.
• W4383105066 title "Cu-MOF/Pd derived oxide nanoparticles based carbon composite - an innovative electrochemical sensing platform for Bisphenol A" @default.
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• W4383105066 doi "https://doi.org/10.1016/j.jallcom.2023.171216" @default.
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