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- W4383313690 abstract "Comprehensive Summary We report an efficient and convergent strategy for the total synthesis of UCS1025A and its diastereomer tetra‐ epi ‐UCS1025A. UCS1025A is a representative member of the naturally occurring pyrrolizidinone polyketides, from which members with potent antibacterial, antifungal, and anticancer activities have been identified. Our approach features a tandem carbonylative Stille cross coupling and Diels‐Alder reaction to forge a key C—C bond and build the trans ‐decalin system. This tandem process utilizes carbon monoxide as a one‐carbon linchpin to stitch a vinyl triflate and a vinylstannane together and form the desired enone moiety for the subsequent intramolecular Diels‐Alder cyclization. Our synthesis also provides a versatile approach for the synthesis of other related pyrrolizidinone‐containing polyketides." @default.
- W4383313690 created "2023-07-07" @default.
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- W4383313690 date "2023-08-17" @default.
- W4383313690 modified "2023-10-18" @default.
- W4383313690 title "Total Synthesis of <scp>UCS1025A</scp> via Tandem Carbonylative Stille Cross Coupling and <scp>Diels‐Alder</scp> Reaction<sup>†</sup>" @default.
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- W4383313690 doi "https://doi.org/10.1002/cjoc.202300331" @default.
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