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- W4383343013 abstract "An amino-functionalized polyhedral oligomeric silsesquioxane (NH2-POSS) was grafted onto molecular chains of a chlorinated alkane-activated polybenzimidazole (CPBI) matrix to fabricate mixed matrix membranes (MMMs) for highly efficient CO2/CH4 separation. The nanocages NH2-POSS contributed significantly to the improvement of the CO2 separation performance. The following explanations were given as the primary causes: first, the nanocages NH2-POSS constructed low-resistance transport pathways for accelerating CO2 transport in MMMs. Second, the amino groups of NH2-POSS provided carriers for CO2, benefiting the improvement of CO2 selectivity. Moreover, the introduced nanocages NH2-POSS reduced the face to face packing and strong hydrogen bonding between CPBI molecule chains to enhance CO2 permeability. As a result, the CO2/CH4 separation performance of CPBI/NH2-POSS MMMs was significantly improved. In particular, compared with the pure CPBI membrane, the CO2 permeability and CO2/CH4 separation factor of CPBI/NH2-POSS-6 MMM were increased by 196.9 and 248.2%, respectively. This work suggested that an efficient strategy for CO2/CH4 separation involved the construction of low-resistance transport pathways by nanocage fillers." @default.
- W4383343013 created "2023-07-07" @default.
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- W4383343013 date "2023-07-06" @default.
- W4383343013 modified "2023-09-23" @default.
- W4383343013 title "Low-Resistance Transport Pathways in POSS/CPBI Mixed Matrix Membranes for Efficient CO<sub>2</sub> Separation" @default.
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- W4383343013 doi "https://doi.org/10.1021/acsanm.3c01733" @default.
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