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- W4383343820 abstract "Abstract Triboraazabutenyne 3 is synthesized by the reaction of diboraazabutenyne 1 with aryl boron dibromide followed by the reduction. The ligand exchange to replace phosphine on the terminal sp 2 B atom with carbene furnishes 4 . 11 B NMR, solid‐state structures, and computational studies disclose that 3 and 4 feature the extremely polarized B=B bond. 4 readily splits the N=N bond of both diazo compound and diazirine under ambient conditions, whereby one nitrogen atom is incorporated into the B=B moiety leading to a neutral diboraazaallene 6 . The mechanism of the reaction between 4 and diazo compound is extensively investigated by density functional theory (DFT) calculations, as well as the isolation of an intermediate." @default.
- W4383343820 created "2023-07-07" @default.
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- W4383343820 date "2023-07-06" @default.
- W4383343820 modified "2023-10-17" @default.
- W4383343820 title "Single‐Nitrogen Atom Incorporation into B=B Bond via the N=N Bond Splitting of Diazo Compound and Diazirine" @default.
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- W4383343820 doi "https://doi.org/10.1002/ange.202306519" @default.
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