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- W4383371805 abstract "The present work demonstrates a solvent-free approach for the homogeneous incorporation of a calcium phosphate (CaP) nanofiller within a biodegradable biocompatible poly(ε-caprolactone) (PCL) polymer. The process involves the nucleation and growth of ions from the simulated physiological fluid into a CaP shell on the surface of the PCL pellets/particles. Subsequently, the capsulated pellets/particles form a biphasic composite after melting within the extruding chamber of a 3D printer, which allows for the 3D printing of a PCL/CaP nanoparticle (NP) composite. The novelty of this work lies in the truly homogeneous size distribution and physical dispersion of the CaP NPs throughout the 3D printed filaments resulting in greater mechanical properties (>2-fold) than PCL alone. In conclusion, a novel solvent-free methodology was developed and characterized for the formation of a new class of additively manufactured biodegradable and biocompatible composites, via the homogenous incorporation of bioactive CaP nanofillers into biodegradable polymers." @default.
- W4383371805 created "2023-07-07" @default.
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- W4383371805 date "2023-10-01" @default.
- W4383371805 modified "2023-10-17" @default.
- W4383371805 title "Unique uniformity of calcium phosphate nanoparticle distribution in polymer substrates for additive manufacturing" @default.
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- W4383371805 doi "https://doi.org/10.1016/j.compositesa.2023.107670" @default.
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