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- W4383377243 abstract "Redox flow batteries have a unique architecture that potentially enables cost-effective long-duration energy storage to address the intermittency introduced by increased renewable integration for the decarbonization of the electric power sector. Targeted molecular engineering has demonstrated electrochemical reversibility in natively redox-inactive ketone molecules in aqueous electrolytes. However, the kinetics of fluorenone-based flow batteries continue to be limited by slow alcohol oxidation. We show how strategically designed proton regulators can accelerate alcohol oxidation and thus enhance battery kinetics. Fluorenone-based flow batteries with the organic additive β-cyclodextrin demonstrate enhanced rate capability, high capacity, and long cycling. This study opens a new avenue to improve the kinetics of aqueous organic flow batteries by modulating the reaction pathway with a homogeneous catalyst." @default.
- W4383377243 created "2023-07-07" @default.
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- W4383377243 date "2023-07-01" @default.
- W4383377243 modified "2023-10-10" @default.
- W4383377243 title "Proton-regulated alcohol oxidation for high-capacity ketone-based flow battery anolyte" @default.
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- W4383377243 doi "https://doi.org/10.1016/j.joule.2023.06.013" @default.
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