Matches in SemOpenAlex for { <https://semopenalex.org/work/W4383499248> ?p ?o ?g. }
- W4383499248 endingPage "34107" @default.
- W4383499248 startingPage "34097" @default.
- W4383499248 abstract "Multimaterial three-dimensional (3D) printing of objects with spatially tunable thermomechanical properties and shape-memory behavior provides an attractive approach toward programmable smart plastics with applications in soft robotics and electronics. To date, digital light processing 3D printing has emerged as one of the fastest manufacturing methods that maintains high precision and resolution. Despite the common utility of semicrystalline polymers in stimuli-responsive materials, few reports exist whereby such polymers have been produced via digital light processing (DLP) 3D printing. Herein, two commodity long-alkyl chain acrylates (C18, stearyl and C12, lauryl) and mixtures therefrom are systematically examined as neat resin components for DLP 3D printing of semicrystalline polymer networks. Tailoring the stearyl/lauryl acrylate ratio results in a wide breadth of thermomechanical properties, including tensile stiffness spanning three orders of magnitude and temperatures from below room temperature (2 °C) to above body temperature (50 °C). This breadth is attributed primarily to changes in the degree of crystallinity. Favorably, the relationship between resin composition and the degree of crystallinity is quadratic, making the thermomechanical properties reproducible and easily programmable. Furthermore, the shape-memory behavior of 3D-printed objects upon thermal cycling is characterized, showing good fatigue resistance and work output. Finally, multimaterial 3D-printed structures with vertical gradation in composition are demonstrated where concomitant localization of thermomechanical properties enables multistage shape-memory and strain-selective behavior. The present platform represents a promising route toward customizable actuators for biomedical applications." @default.
- W4383499248 created "2023-07-08" @default.
- W4383499248 creator A5004520576 @default.
- W4383499248 creator A5015417245 @default.
- W4383499248 creator A5026073052 @default.
- W4383499248 creator A5028076982 @default.
- W4383499248 creator A5047940368 @default.
- W4383499248 creator A5088969672 @default.
- W4383499248 creator A5092420302 @default.
- W4383499248 date "2023-07-07" @default.
- W4383499248 modified "2023-09-25" @default.
- W4383499248 title "Digital Light Processing 3D Printing of Soft Semicrystalline Acrylates with Localized Shape Memory and Stiffness Control" @default.
- W4383499248 cites W1998863328 @default.
- W4383499248 cites W2013880912 @default.
- W4383499248 cites W2016421336 @default.
- W4383499248 cites W2020564360 @default.
- W4383499248 cites W2024129669 @default.
- W4383499248 cites W2030405671 @default.
- W4383499248 cites W2057473899 @default.
- W4383499248 cites W2125348994 @default.
- W4383499248 cites W2144815200 @default.
- W4383499248 cites W2232842705 @default.
- W4383499248 cites W2271671302 @default.
- W4383499248 cites W2326027541 @default.
- W4383499248 cites W2328466364 @default.
- W4383499248 cites W2343414827 @default.
- W4383499248 cites W2519831124 @default.
- W4383499248 cites W2520809832 @default.
- W4383499248 cites W2566193558 @default.
- W4383499248 cites W2660587980 @default.
- W4383499248 cites W2735182557 @default.
- W4383499248 cites W2806061811 @default.
- W4383499248 cites W2809333160 @default.
- W4383499248 cites W2884140776 @default.
- W4383499248 cites W2889149949 @default.
- W4383499248 cites W2897750711 @default.
- W4383499248 cites W2909857791 @default.
- W4383499248 cites W2912101418 @default.
- W4383499248 cites W2916478639 @default.
- W4383499248 cites W2942580786 @default.
- W4383499248 cites W2946073846 @default.
- W4383499248 cites W2979159125 @default.
- W4383499248 cites W3003085082 @default.
- W4383499248 cites W3010619035 @default.
- W4383499248 cites W3016672182 @default.
- W4383499248 cites W3022580245 @default.
- W4383499248 cites W3023001773 @default.
- W4383499248 cites W3033550606 @default.
- W4383499248 cites W3038560046 @default.
- W4383499248 cites W3110855734 @default.
- W4383499248 cites W3113174218 @default.
- W4383499248 cites W3113666519 @default.
- W4383499248 cites W3179821397 @default.
- W4383499248 cites W3180058821 @default.
- W4383499248 cites W3192713642 @default.
- W4383499248 cites W3195117206 @default.
- W4383499248 cites W3197197101 @default.
- W4383499248 cites W4206535797 @default.
- W4383499248 cites W4210630899 @default.
- W4383499248 cites W4210689516 @default.
- W4383499248 cites W4211178353 @default.
- W4383499248 cites W4212773921 @default.
- W4383499248 cites W4212805852 @default.
- W4383499248 cites W4220670648 @default.
- W4383499248 cites W4221062205 @default.
- W4383499248 cites W4224126979 @default.
- W4383499248 cites W4282593605 @default.
- W4383499248 cites W4282959751 @default.
- W4383499248 cites W4285175233 @default.
- W4383499248 cites W4285798864 @default.
- W4383499248 cites W4293178679 @default.
- W4383499248 cites W4295902285 @default.
- W4383499248 cites W4305040323 @default.
- W4383499248 cites W4307404726 @default.
- W4383499248 cites W4308547953 @default.
- W4383499248 cites W4312195052 @default.
- W4383499248 cites W4321004030 @default.
- W4383499248 cites W4321764894 @default.
- W4383499248 cites W4323858400 @default.
- W4383499248 doi "https://doi.org/10.1021/acsami.3c07172" @default.
- W4383499248 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37418641" @default.
- W4383499248 hasPublicationYear "2023" @default.
- W4383499248 type Work @default.
- W4383499248 citedByCount "0" @default.
- W4383499248 crossrefType "journal-article" @default.
- W4383499248 hasAuthorship W4383499248A5004520576 @default.
- W4383499248 hasAuthorship W4383499248A5015417245 @default.
- W4383499248 hasAuthorship W4383499248A5026073052 @default.
- W4383499248 hasAuthorship W4383499248A5028076982 @default.
- W4383499248 hasAuthorship W4383499248A5047940368 @default.
- W4383499248 hasAuthorship W4383499248A5088969672 @default.
- W4383499248 hasAuthorship W4383499248A5092420302 @default.
- W4383499248 hasConcept C154945302 @default.
- W4383499248 hasConcept C159985019 @default.
- W4383499248 hasConcept C172707124 @default.
- W4383499248 hasConcept C185698529 @default.
- W4383499248 hasConcept C192562407 @default.
- W4383499248 hasConcept C2776058767 @default.