Matches in SemOpenAlex for { <https://semopenalex.org/work/W4383602017> ?p ?o ?g. }
Showing items 1 to 70 of
70
with 100 items per page.
- W4383602017 endingPage "91" @default.
- W4383602017 startingPage "45" @default.
- W4383602017 abstract "The concern is mainly with internal energy, heat, work, and the first law of thermodynamics. Mathematical statements are given for the system and surroundings, the system alone when the system does work on the surroundings, or against constant external pressure. The relationships among the change in the internal energy, work, and heat for isothermal expansion of an ideal gas and real gas are examined. First, when the expansion takes place: into the vacuum, against constant pressure (irreversible), or against changing external pressure (reversible). The molar heat of vaporization and the consequence of the isothermal liquid vaporization, heating a substance at constant volume, and the adiabatic system are studied. Useful relationships among pressure, volume, and temperature for adiabatic change are also examined. The molar change in the internal energy for a chemical reaction is explored. Then we show how to calculate bond enthalpy, and types of chemical and physical enthalpy changes, e.g., enthalpy of solution of solid compound, enthalpy of neutralization, enthalpy of precipitation, enthalpy of combustion, and enthalpy of formation. Next, the basis of the thermochemistry, law of Lavoisier, Laplace, Hess' Law, the heat of formation, mathematic statement for enthalpy, at a constant temperature, and constant pressure are developed. Emphasis is also placed on the correlation between enthalpy and temperature change, heat capacity and enthalpy, constant pressure and constant volume heat capacities, heat capacity and degree of freedom, and finally between heat capacity and reaction enthalpy. Total and partial derivatives with respect to the temperature, pressure, or volume are examined and used to understand the internal pressure and internal energy. Finally, we introduce the Joule-Thompson effect, define the Joule-Thomson coefficient, calorimetry, and bomb calorimeter." @default.
- W4383602017 created "2023-07-08" @default.
- W4383602017 creator A5071209765 @default.
- W4383602017 creator A5079194629 @default.
- W4383602017 date "2023-01-01" @default.
- W4383602017 modified "2023-09-25" @default.
- W4383602017 title "Work, heat, internal energy, and enthalpy" @default.
- W4383602017 doi "https://doi.org/10.1016/b978-0-443-15295-5.00013-2" @default.
- W4383602017 hasPublicationYear "2023" @default.
- W4383602017 type Work @default.
- W4383602017 citedByCount "0" @default.
- W4383602017 crossrefType "book-chapter" @default.
- W4383602017 hasAuthorship W4383602017A5071209765 @default.
- W4383602017 hasAuthorship W4383602017A5079194629 @default.
- W4383602017 hasConcept C109663097 @default.
- W4383602017 hasConcept C121332964 @default.
- W4383602017 hasConcept C129564387 @default.
- W4383602017 hasConcept C132704077 @default.
- W4383602017 hasConcept C133347239 @default.
- W4383602017 hasConcept C185592680 @default.
- W4383602017 hasConcept C18762648 @default.
- W4383602017 hasConcept C190764699 @default.
- W4383602017 hasConcept C199519896 @default.
- W4383602017 hasConcept C205963292 @default.
- W4383602017 hasConcept C29700514 @default.
- W4383602017 hasConcept C3288061 @default.
- W4383602017 hasConcept C39519442 @default.
- W4383602017 hasConcept C50517652 @default.
- W4383602017 hasConcept C60205243 @default.
- W4383602017 hasConcept C60778519 @default.
- W4383602017 hasConcept C65494353 @default.
- W4383602017 hasConcept C79289859 @default.
- W4383602017 hasConcept C97355855 @default.
- W4383602017 hasConceptScore W4383602017C109663097 @default.
- W4383602017 hasConceptScore W4383602017C121332964 @default.
- W4383602017 hasConceptScore W4383602017C129564387 @default.
- W4383602017 hasConceptScore W4383602017C132704077 @default.
- W4383602017 hasConceptScore W4383602017C133347239 @default.
- W4383602017 hasConceptScore W4383602017C185592680 @default.
- W4383602017 hasConceptScore W4383602017C18762648 @default.
- W4383602017 hasConceptScore W4383602017C190764699 @default.
- W4383602017 hasConceptScore W4383602017C199519896 @default.
- W4383602017 hasConceptScore W4383602017C205963292 @default.
- W4383602017 hasConceptScore W4383602017C29700514 @default.
- W4383602017 hasConceptScore W4383602017C3288061 @default.
- W4383602017 hasConceptScore W4383602017C39519442 @default.
- W4383602017 hasConceptScore W4383602017C50517652 @default.
- W4383602017 hasConceptScore W4383602017C60205243 @default.
- W4383602017 hasConceptScore W4383602017C60778519 @default.
- W4383602017 hasConceptScore W4383602017C65494353 @default.
- W4383602017 hasConceptScore W4383602017C79289859 @default.
- W4383602017 hasConceptScore W4383602017C97355855 @default.
- W4383602017 hasLocation W43836020171 @default.
- W4383602017 hasOpenAccess W4383602017 @default.
- W4383602017 hasPrimaryLocation W43836020171 @default.
- W4383602017 hasRelatedWork W1984087998 @default.
- W4383602017 hasRelatedWork W2013293723 @default.
- W4383602017 hasRelatedWork W2027019931 @default.
- W4383602017 hasRelatedWork W2061471512 @default.
- W4383602017 hasRelatedWork W2716332539 @default.
- W4383602017 hasRelatedWork W2993433750 @default.
- W4383602017 hasRelatedWork W3023541488 @default.
- W4383602017 hasRelatedWork W4235213758 @default.
- W4383602017 hasRelatedWork W4237302513 @default.
- W4383602017 hasRelatedWork W2480193690 @default.
- W4383602017 isParatext "false" @default.
- W4383602017 isRetracted "false" @default.
- W4383602017 workType "book-chapter" @default.