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- W4383646039 abstract "NO2 is a very dangerous and toxic gas and is prone to cause acid rain in high humidity environments, so it is essential to prepare a real-time monitoring and humidity immunity NO2 sensor. WO3 nanomaterials are commonly applied to detect NO2, but their poor immunity to humidity is still a critical limitation for the application. ZnO-nanorod-decorated WO3 nanosheets coated with ZIF-71 (ZnO@ZIF-71/WO3) composites prepared by an in situ growth method displayed excellent gas sensing performance and good humidity immunity to detect NO2. Compared to WO3 nanosheets and ZnO-nanorod-decorated WO3 nanosheets (ZnO/WO3) heterojunction composites grown on ceramic substrates in situ, ZnO@ZIF-71/WO3 presented excellent selectivity, good long-term stability, and a remarkably high response of about 947.96 to 100 ppm NO2 at 180 °C, which is 3.07 times higher than that of the ZnO/WO3 sensor and 4.59 times higher than that of the pure WO3 sensor. Even at a relative humidity of 85%, the response of ZnO@ZIF-71/WO3 to NO2 remained essentially constant. The functional ZIF-71 layer not only improved the humidity immunity of ZnO@ZIF-71/WO3 but also enhanced the sensitivity and selectivity performance to NO2 at low operating temperatures. The ZnO@ZIF-71/WO3 sensor still provided a response of 88.41 to 100 ppm NO2 at room temperature." @default.
- W4383646039 created "2023-07-09" @default.
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- W4383646039 date "2023-07-08" @default.
- W4383646039 modified "2023-10-14" @default.
- W4383646039 title "Heterojunctions of ZnO-Nanorod-Decorated WO<sub>3</sub> Nanosheets Coated with ZIF-71 for Humidity-Independent NO<sub>2</sub> Sensing" @default.
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- W4383646039 doi "https://doi.org/10.1021/acsanm.3c01955" @default.
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