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- W4383671809 abstract "Layered AxMO2 phases attract great attention as electrode materials for high-energy density batteries. The main structural variants in this family are know n as O3, P2 and P3. Previous experimental data and theoretical considerations have shown that prismatic structures with A = Na or K can only be stable at x values significantly lower than unity, typically 0.6–0.8 for P2 and 0.5–06 for P3 (if any). This was challenged by recent reports on P3-type Na0.9(Fe0.5Mn0.5)O2 and Na(Cu0.2Fe0.1Mn0.7)O2. We found, however, that the reported XRD patterns strongly disagree with the reported structures and compositions. For the former, actual lattice parameters correspond to an x value much lower than 0.9, and the latter is actually P2 type with x close to 0.74." @default.
- W4383671809 created "2023-07-09" @default.
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- W4383671809 date "2023-10-01" @default.
- W4383671809 modified "2023-10-10" @default.
- W4383671809 title "No P3-type phase of NaxMO2 with x close to unity" @default.
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- W4383671809 doi "https://doi.org/10.1016/j.jssc.2023.124209" @default.
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