Matches in SemOpenAlex for { <https://semopenalex.org/work/W4383710587> ?p ?o ?g. }
- W4383710587 endingPage "5219" @default.
- W4383710587 startingPage "5214" @default.
- W4383710587 abstract "Rapid access to 2,2-difluorobicylco[1.1.1]pentanes is enabled from an α-allyldiazoacetate precursor in a one-pot process through cyclopropanation to afford a 3-aryl bicyclo[1.1.0]butane, followed by reaction with difluorocarbene in the same reaction flask. The modular synthesis of these diazo compounds affords novel 2,2-difluorobicyclo[1.1.1]pentanes that were inaccessible through previously reported methods. The reactions of chiral 2-arylbicyclo[1.1.0]butanes in the same manner generate altogether different products with high asymmetric induction, methylene-difluorocyclobutanes. Larger ring systems including bicyclo[3.1.0]hexanes are also rapidly furnished due to the modular nature of the diazo starting material." @default.
- W4383710587 created "2023-07-11" @default.
- W4383710587 creator A5013658392 @default.
- W4383710587 creator A5083948798 @default.
- W4383710587 date "2023-07-10" @default.
- W4383710587 modified "2023-10-14" @default.
- W4383710587 title "One-Pot Synthesis of Difluorobicyclo[1.1.1]pentanes from α-Allyldiazoacetates" @default.
- W4383710587 cites W1995414684 @default.
- W4383710587 cites W2022658237 @default.
- W4383710587 cites W2027703345 @default.
- W4383710587 cites W2038110172 @default.
- W4383710587 cites W2051156996 @default.
- W4383710587 cites W2179070715 @default.
- W4383710587 cites W2312978014 @default.
- W4383710587 cites W2321926939 @default.
- W4383710587 cites W2333507101 @default.
- W4383710587 cites W2598194541 @default.
- W4383710587 cites W2752105738 @default.
- W4383710587 cites W2782667921 @default.
- W4383710587 cites W2792842263 @default.
- W4383710587 cites W2898494489 @default.
- W4383710587 cites W2910203594 @default.
- W4383710587 cites W2912273886 @default.
- W4383710587 cites W2939131903 @default.
- W4383710587 cites W2962425302 @default.
- W4383710587 cites W2974517436 @default.
- W4383710587 cites W2975646483 @default.
- W4383710587 cites W2982053328 @default.
- W4383710587 cites W2995816326 @default.
- W4383710587 cites W3002784834 @default.
- W4383710587 cites W3006162111 @default.
- W4383710587 cites W3019790436 @default.
- W4383710587 cites W3044591481 @default.
- W4383710587 cites W3081013869 @default.
- W4383710587 cites W3083018736 @default.
- W4383710587 cites W3089007925 @default.
- W4383710587 cites W3099002743 @default.
- W4383710587 cites W3104641347 @default.
- W4383710587 cites W3135457188 @default.
- W4383710587 cites W3176444471 @default.
- W4383710587 cites W3182060631 @default.
- W4383710587 cites W3204791367 @default.
- W4383710587 cites W4200312784 @default.
- W4383710587 cites W4220854460 @default.
- W4383710587 cites W4233141962 @default.
- W4383710587 cites W4282923154 @default.
- W4383710587 cites W4283575334 @default.
- W4383710587 cites W4290975908 @default.
- W4383710587 cites W4293425690 @default.
- W4383710587 cites W4295100677 @default.
- W4383710587 cites W4308636731 @default.
- W4383710587 cites W4309682003 @default.
- W4383710587 cites W4317951832 @default.
- W4383710587 cites W4327681997 @default.
- W4383710587 doi "https://doi.org/10.1021/acs.orglett.3c01664" @default.
- W4383710587 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37427998" @default.
- W4383710587 hasPublicationYear "2023" @default.
- W4383710587 type Work @default.
- W4383710587 citedByCount "1" @default.
- W4383710587 countsByYear W43837105872023 @default.
- W4383710587 crossrefType "journal-article" @default.
- W4383710587 hasAuthorship W4383710587A5013658392 @default.
- W4383710587 hasAuthorship W4383710587A5083948798 @default.
- W4383710587 hasBestOaLocation W43837105871 @default.
- W4383710587 hasConcept C161790260 @default.
- W4383710587 hasConcept C178790620 @default.
- W4383710587 hasConcept C185592680 @default.
- W4383710587 hasConcept C24961977 @default.
- W4383710587 hasConcept C2776904781 @default.
- W4383710587 hasConcept C2777052750 @default.
- W4383710587 hasConcept C2777084352 @default.
- W4383710587 hasConcept C2777454769 @default.
- W4383710587 hasConcept C2778717364 @default.
- W4383710587 hasConcept C2780263894 @default.
- W4383710587 hasConcept C2781076698 @default.
- W4383710587 hasConceptScore W4383710587C161790260 @default.
- W4383710587 hasConceptScore W4383710587C178790620 @default.
- W4383710587 hasConceptScore W4383710587C185592680 @default.
- W4383710587 hasConceptScore W4383710587C24961977 @default.
- W4383710587 hasConceptScore W4383710587C2776904781 @default.
- W4383710587 hasConceptScore W4383710587C2777052750 @default.
- W4383710587 hasConceptScore W4383710587C2777084352 @default.
- W4383710587 hasConceptScore W4383710587C2777454769 @default.
- W4383710587 hasConceptScore W4383710587C2778717364 @default.
- W4383710587 hasConceptScore W4383710587C2780263894 @default.
- W4383710587 hasConceptScore W4383710587C2781076698 @default.
- W4383710587 hasFunder F4320337393 @default.
- W4383710587 hasIssue "28" @default.
- W4383710587 hasLocation W43837105871 @default.
- W4383710587 hasLocation W43837105872 @default.
- W4383710587 hasOpenAccess W4383710587 @default.
- W4383710587 hasPrimaryLocation W43837105871 @default.
- W4383710587 hasRelatedWork W1964293454 @default.
- W4383710587 hasRelatedWork W1979140863 @default.
- W4383710587 hasRelatedWork W1996161613 @default.
- W4383710587 hasRelatedWork W2069959101 @default.
- W4383710587 hasRelatedWork W2079313185 @default.
- W4383710587 hasRelatedWork W2085487425 @default.