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- W4383755462 abstract "Two new octaketides, cytosporones W (1) and X (2), along with eight known cytosporone derivatives [(±)-3-9], were isolated from mangrove endophytic fungus Diaporthe sp. ZJHJYZ-1. Compounds 1 and 2 were a pair of epimers, whose configuration of C-1 could mutually convert, causing racemization of the lactone ring. The planar structures of compounds were elucidated through detailed 1D, 2D NMR, and HR-ESI-MS analysis. ECD spectra comparison and modified Mosher ester method were applied to determine the absolute configuration of 1 and 2. In bioassays, (±)-3 exhibited promising inhibitory activities against Bacillus subtilis, Pseudomonas aeruginosa, and Penicillium italicum with MIC, respectively, for 12.5, 12.5, and 3.13 μM." @default.
- W4383755462 created "2023-07-11" @default.
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- W4383755462 date "2023-07-10" @default.
- W4383755462 modified "2023-10-17" @default.
- W4383755462 title "Cytosporones W and X: Two Mutually Converting Epimers from a Mangrove Endophytic Fungus <i>Diaporthe</i> sp. ZJHJYZ-1" @default.
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- W4383755462 doi "https://doi.org/10.1021/acsomega.3c03862" @default.
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