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- W4383757191 abstract "Herein, we unveiled an efficient intramolecular umpolung chemodivergent cascade route for synthesizing 1-indanones via precisely switching the umpolung reactivity between the α-diketone and π-allyl Pd complex. This successful merging of chemodivergent and umpolung strategies is accomplished by employing a Pd catalyst and Et2Zn, which provides a broad array of 1-indanones with good yield and selectivity. The salient feature involves the amphiphilic behaviors of both α-diketone and allyl functionality in two engineered mild reaction conditions. Furthermore, scale up synthesis and postsynthetic transformations amplify the significance of the current protocol. Additionally, we have achieved the diastereomers of both ether and alcohol derivatives of 1-indanone efficiently via synthetic transformation." @default.
- W4383757191 created "2023-07-11" @default.
- W4383757191 creator A5039010928 @default.
- W4383757191 creator A5070213176 @default.
- W4383757191 date "2023-07-10" @default.
- W4383757191 modified "2023-09-26" @default.
- W4383757191 title "Pd-Catalyzed Chemodivergent Synthesis of 1-Indanones via Diethyl Zinc-Mediated Precise Switching of Umpolung Reactivity" @default.
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- W4383757191 doi "https://doi.org/10.1021/acscatal.3c01988" @default.
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