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• W4384025667 abstract "To study and comprehend the molecular interactions between ionic liquids (ILs) such as 1-ethyl-3-methylimidazolium bromide [EMIm]Br, 1-butyl-3-methylimidazolium bromide [BMIm]Br, and 1-hexyl-3-methylimidazolium bromide [HMIm]Br, and the antidepressant drug-nortriptyline hydrochloride (NTPH), we have examined the volumetric, acoustic, and viscometer properties of the binary and ternary solutions of different concentrations at different temperatures 288.15–318.15 K in the temperature interval of 10 K. The intermolecular interactions have been appraised and identified on the basis of different parameters, i.e., apparent molar properties (VΦ, Ks, Φ), limiting apparent molar properties (VoΦ, Kos,Φ), viscosity coefficients A and B, limiting apparent molar transfer properties (VoΦ,tr, Kos,Φ,tr), viscosity B-coefficient of transfer (Btr). Pair and triplet interaction coefficients are also determined using McMillan-Mayer theory. Based on the cosphere overlap model, the positive transfer values (VoΦ,tr, Kos,Φ,tr) demonstrate that ionic-hydrophilic and hydrophilic–hydrophilic interactions are dominant between NTPH-IL solutions. Additionally, the strength of these interactions increases as the alkyl chain length of the imidazolium ionic liquid increases. Furthermore, the negative values of temperature derivatives of B-coefficients (dB/dT) and the positive values of Hepler’s constant confirms the structure making nature of NTPH." @default.
• W4384025667 created "2023-07-13" @default.
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• W4384025667 date "2023-07-12" @default.
• W4384025667 modified "2023-09-25" @default.
• W4384025667 title "Molecular Interaction Studies of an Antidepressant Drug with Imidazolium-Based Ionic Liquids in an Aqueous System: A Volumetric, Acoustic, and Viscometric Approach" @default.
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• W4384025667 doi "https://doi.org/10.1021/acs.jced.2c00640" @default.
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