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- W4384037850 endingPage "132041" @default.
- W4384037850 startingPage "132041" @default.
- W4384037850 abstract "Due to frequent petrochemical spills, environmental pollution and the threat of secondary marine fires have arisen, necessitating an urgent need for petrochemical spill treatment strategies with high-performance oil-water separation capabilities. To address the challenges of poor durability, instability in hydrophobic conditions, and difficulty in absorbing high-viscosity crude oil associated with hydrophobic absorbent materials, the authors of this study took inspiration from the unique micro and nanostructures of springtails' water-repellent skin. We engineered a superhydrophobic melamine sponge using interfacial assembly techniques designated as [email protected]@[email protected] This material demonstrated improved mechanical and chemical durability, enhanced photothermal performance, and reduced fire risk. The metal-organic framework (MOF)-derived cobalt-iron Prussian blue analog (CoFe-PBA) was firmly anchored to the sponge framework by the chelation of cobalt ions using polydopamine (PDA). The results demonstrated that [email protected]@[email protected] demonstrated excellent superhydrophobicity (WCA=163.5°) and oil absorption capacity (53.4-97.5 g/g), maintaining high durability even after 20 cycles of absorption-squeezing. Additionally, it could still exhibit excellent mechanical properties, hydrophobic stability, and absorption performance across a wide temperature range (0-100°C), pH range (1-14), and high compression strength (ε=80%), with excellent mechanical/chemical durability. Furthermore, [email protected]@[email protected] demonstrated remarkable photothermal performance and low fire risk, offering efficient, safe, and sustainable practical value for effective petrochemical spill treatment." @default.
- W4384037850 created "2023-07-13" @default.
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- W4384037850 date "2023-10-01" @default.
- W4384037850 modified "2023-10-11" @default.
- W4384037850 title "A biomimetic design for efficient petrochemical spill disposal: CoFe-PBA modified superhydrophobic melamine sponge with mechanical/chemical durability and low fire risk" @default.
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- W4384037850 doi "https://doi.org/10.1016/j.jhazmat.2023.132041" @default.
- W4384037850 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37487334" @default.
- W4384037850 hasPublicationYear "2023" @default.
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