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• W4384126426 abstract "The first PtIV-containing discrete polyoxoplatinate(II) [PtIVPtII6O6(AsO2(CH3)2)6]2- (Pt7) and polyoxopalladate(II) [PtIVPdII6O6(AsO2(CH3)2)6]2- (PtPd6) have been prepared and characterized in the solid state, in solution, and in the gas phase. The molecular structures of the noble metal-oxo clusters Pt7 and PtPd6 comprise a central, octahedral PtIVO6 hetero group surrounded by six square-planar MO4 (M = PtII, PdII) units, which are capped by six dimethylarsinate ligands. The polyanions were prepared under simple one-pot aqueous solution conditions by reacting H2Pt(OH)6 with either K2PtCl4 or Pd(NO3)2 in sodium dimethylarsinate buffer (pH 7) at 80 °C. Catalytic studies were performed on Pt7 supported on SBA15-apts for o-xylene hydrogenation at 300 °C and 90 bar H2 pressure and indicated excellent activity and recyclability with low activation temperature." @default.
• W4384126426 created "2023-07-14" @default.
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• W4384126426 date "2023-07-13" @default.
• W4384126426 modified "2023-09-30" @default.
• W4384126426 title "Pt^IV-Containing Hexaplatinate(II) [Pt^IVPt^II₆O₆(AsO₂(CH₃)₂)₆]^2– and Hexapalladate(II) [Pt^IVPd^II₆O₆(AsO₂(CH₃)₂)₆]^2–" @default.
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• W4384126426 doi "https://doi.org/10.1021/acs.inorgchem.3c00832" @default.
• W4384126426 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37440284" @default.
• W4384126426 hasPublicationYear "2023" @default.
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