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- W4384126768 abstract "Herein, a Pd/Cu bimetallic-catalyzed direct C–H heteroarylation of pyridines via the traceless protecting group strategy is described. A series of N-methyl-activated pyridines and 1-methylindoles are coupled with high regioselectivity to produce the corresponding 3-(pyridin-2-yl)indoles in moderate to good yields, wherein related electron-rich heterocycles (e.g., indole, 1-methylpyrrole, benzofuran, benzo[b]thiophene) are also applicable. Streamlined operation, good functional group tolerance, and late-stage modifications make this twofold C–H activation protocol an attractive route for the synthesis of 3-(pyridin-2-yl)indole derivatives." @default.
- W4384126768 created "2023-07-14" @default.
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- W4384126768 date "2023-07-13" @default.
- W4384126768 modified "2023-10-16" @default.
- W4384126768 title "Copper-Mediated and Palladium-Catalyzed Cross-Coupling of Indoles and <i>N</i>-Methylpyridinium Salts: A Practical Way to Prepare 3-(Pyridin-2-yl)indoles" @default.
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- W4384126768 doi "https://doi.org/10.1021/acs.orglett.3c01624" @default.
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