Matches in SemOpenAlex for { <https://semopenalex.org/work/W4384131176> ?p ?o ?g. }
Showing items 1 to 95 of
95
with 100 items per page.
- W4384131176 endingPage "1089" @default.
- W4384131176 startingPage "1089" @default.
- W4384131176 abstract "An unusual heterobimetallic volatile compound [Pb2Co5(acac)14] was synthesized by the gas phase/solid-state technique. The preparation can be readily scaled up using the solution approach. X-ray powder diffraction, ICP-OES analysis, and DART mass spectrometry were engaged to confirm the composition and purity of heterobimetallic complex. The composition is unique among the large family of lead(tin): transition metal = 2:1, 1:1, and 1:2 β-diketonates compounds that are mostly represented by coordination polymers. The molecular structure of the complex was elucidated by synchrotron single crystal X-ray diffraction to reveal the unique heptanuclear moiety {Co(acac)2[Pb(acac)2-Co(acac)2-Co(acac)2]2} built upon bridging interactions of acetylacetonate oxygens to neighboring metal centers that bring their coordination numbers to six. The appearance of unique heptanuclear assembly can be attributed to the fact that the [Co(acac)2] units feature both cis- and trans-bis-bridging modes, making the polynuclear moiety rather flexible. This type of octahedral coordination is relatively unique among known lead(tin)-3d transition metal β-diketonates. Due to the high-volatility, [Pb2Co5(acac)14] can be potentially applied as a MOCVD precursor for the low-temperature preparation of lead-containing functional materials." @default.
- W4384131176 created "2023-07-14" @default.
- W4384131176 creator A5025890771 @default.
- W4384131176 creator A5056836368 @default.
- W4384131176 creator A5083286960 @default.
- W4384131176 date "2023-07-12" @default.
- W4384131176 modified "2023-09-29" @default.
- W4384131176 title "Synthesis, Structure, and Characterizations of a Heterobimetallic Heptanuclear Complex [Pb2Co5(acac)14]" @default.
- W4384131176 cites W1928960752 @default.
- W4384131176 cites W1969360633 @default.
- W4384131176 cites W1970452244 @default.
- W4384131176 cites W1981683388 @default.
- W4384131176 cites W1997884371 @default.
- W4384131176 cites W2003783992 @default.
- W4384131176 cites W2023596643 @default.
- W4384131176 cites W2027965569 @default.
- W4384131176 cites W2031349670 @default.
- W4384131176 cites W2047845277 @default.
- W4384131176 cites W2049440437 @default.
- W4384131176 cites W2054794459 @default.
- W4384131176 cites W2059205366 @default.
- W4384131176 cites W2069883454 @default.
- W4384131176 cites W2077274421 @default.
- W4384131176 cites W2084305886 @default.
- W4384131176 cites W2089037437 @default.
- W4384131176 cites W2092054241 @default.
- W4384131176 cites W2092600920 @default.
- W4384131176 cites W2099852542 @default.
- W4384131176 cites W2111831948 @default.
- W4384131176 cites W2132454074 @default.
- W4384131176 cites W2315617430 @default.
- W4384131176 cites W2319682064 @default.
- W4384131176 cites W2738475109 @default.
- W4384131176 cites W2740663794 @default.
- W4384131176 cites W2748940590 @default.
- W4384131176 cites W2804925368 @default.
- W4384131176 cites W2956125260 @default.
- W4384131176 doi "https://doi.org/10.3390/cryst13071089" @default.
- W4384131176 hasPublicationYear "2023" @default.
- W4384131176 type Work @default.
- W4384131176 citedByCount "0" @default.
- W4384131176 crossrefType "journal-article" @default.
- W4384131176 hasAuthorship W4384131176A5025890771 @default.
- W4384131176 hasAuthorship W4384131176A5056836368 @default.
- W4384131176 hasAuthorship W4384131176A5083286960 @default.
- W4384131176 hasBestOaLocation W43841311761 @default.
- W4384131176 hasConcept C106773901 @default.
- W4384131176 hasConcept C115624301 @default.
- W4384131176 hasConcept C145148216 @default.
- W4384131176 hasConcept C161790260 @default.
- W4384131176 hasConcept C178790620 @default.
- W4384131176 hasConcept C185039092 @default.
- W4384131176 hasConcept C185592680 @default.
- W4384131176 hasConcept C198819137 @default.
- W4384131176 hasConcept C2776568683 @default.
- W4384131176 hasConcept C33559828 @default.
- W4384131176 hasConcept C525849907 @default.
- W4384131176 hasConcept C544153396 @default.
- W4384131176 hasConcept C71240020 @default.
- W4384131176 hasConcept C8010536 @default.
- W4384131176 hasConceptScore W4384131176C106773901 @default.
- W4384131176 hasConceptScore W4384131176C115624301 @default.
- W4384131176 hasConceptScore W4384131176C145148216 @default.
- W4384131176 hasConceptScore W4384131176C161790260 @default.
- W4384131176 hasConceptScore W4384131176C178790620 @default.
- W4384131176 hasConceptScore W4384131176C185039092 @default.
- W4384131176 hasConceptScore W4384131176C185592680 @default.
- W4384131176 hasConceptScore W4384131176C198819137 @default.
- W4384131176 hasConceptScore W4384131176C2776568683 @default.
- W4384131176 hasConceptScore W4384131176C33559828 @default.
- W4384131176 hasConceptScore W4384131176C525849907 @default.
- W4384131176 hasConceptScore W4384131176C544153396 @default.
- W4384131176 hasConceptScore W4384131176C71240020 @default.
- W4384131176 hasConceptScore W4384131176C8010536 @default.
- W4384131176 hasFunder F4320306076 @default.
- W4384131176 hasIssue "7" @default.
- W4384131176 hasLocation W43841311761 @default.
- W4384131176 hasOpenAccess W4384131176 @default.
- W4384131176 hasPrimaryLocation W43841311761 @default.
- W4384131176 hasRelatedWork W1967528327 @default.
- W4384131176 hasRelatedWork W1987623416 @default.
- W4384131176 hasRelatedWork W2019772008 @default.
- W4384131176 hasRelatedWork W2045568882 @default.
- W4384131176 hasRelatedWork W2056780726 @default.
- W4384131176 hasRelatedWork W2069277255 @default.
- W4384131176 hasRelatedWork W2378479697 @default.
- W4384131176 hasRelatedWork W4223427855 @default.
- W4384131176 hasRelatedWork W4254890894 @default.
- W4384131176 hasRelatedWork W2048926559 @default.
- W4384131176 hasVolume "13" @default.
- W4384131176 isParatext "false" @default.
- W4384131176 isRetracted "false" @default.
- W4384131176 workType "article" @default.