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- W4384154339 abstract "Abstract Isolated clusters are ideal systems for tailoring molecule-based magnets and investigating the evolution of magnetic order from microscopic to macroscopic regime. We have prepared pure Fe n – ( n = 7-31) clusters and observed their gas-collisional reactions with oxygen in a flow tube reactor. Interestingly, only the larger Fe n – ( n ≥ 15) clusters support the observation of O 2 -intake, while the smaller clusters Fe n – ( n = 7-14) are nearly nonreactive. What is more interesting is that Fe 17 O 10 – shows up with prominent abundance in the mass spectra indicative of its distinct inertness. In combination with DFT calculations, we unveil the stability of Fe 17 O 10 – within an interesting acordion-like structure and elucidate the spin accommodation in such a strongly ferromagnetic iron cluster oxide." @default.
- W4384154339 created "2023-07-14" @default.
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- W4384154339 date "2023-07-13" @default.
- W4384154339 modified "2023-10-14" @default.
- W4384154339 title "A stable and strongly ferromagnetic Fe17O10– cluster with an accordion-like structure" @default.
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- W4384154339 doi "https://doi.org/10.1038/s42004-023-00952-z" @default.
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