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- W4384154881 abstract "A regioselective direct carboxamidation reaction of 2-indolylmethanols with readily available isocyanoesters/isocyanides has been reported in this work. The reaction was catalyzed by Bronsted acid such as p-TsOH to deliver the benzylic regioselective amides in 67-86% yield under mild conditions. The developed methodology provides alternative access to traditional metal-free carboxamidation via C-C and C-O bond formation with high atom economy. Furthermore, the developed approach was diversified to synthesize chiral indole-2-carboxamide derivatives with a moderate enantiomeric excess (61-73% ee) using an (R)-chiral phosphoric acid." @default.
- W4384154881 created "2023-07-14" @default.
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- W4384154881 date "2023-07-13" @default.
- W4384154881 modified "2023-09-25" @default.
- W4384154881 title "Bronsted Acid-Catalyzed Regioselective Carboxamidation of 2-Indolylmethanols with Isonitriles" @default.
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- W4384154881 doi "https://doi.org/10.1021/acs.joc.2c02816" @default.
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