Matches in SemOpenAlex for { <https://semopenalex.org/work/W4384157473> ?p ?o ?g. }
- W4384157473 endingPage "100042" @default.
- W4384157473 startingPage "100042" @default.
- W4384157473 abstract "The aminomethyl cyclopalladated complex is identified as a key intermediate for promoting the C–N bond activation of tertiary amines via reductive elimination and oxidative addition sequence. This strategy has enabled a palladium-catalyzed ring-closing reaction of enynols with aminals via methylene transfer and C–N bond activation, which provides rapid access to densely functionalized O-heterocycle containing allenic amines. The dual roles of the cyclopalladated complex, first as an aminomethylene-carrying reagent and then as a catalyst for C–N bond activation, have enabled a rare cascade redox-neutral methylene transfer and cyclization process that can simultaneously construct O-heterocycle framework and allenic amine functionality." @default.
- W4384157473 created "2023-07-14" @default.
- W4384157473 creator A5014364892 @default.
- W4384157473 creator A5063833862 @default.
- W4384157473 creator A5067490406 @default.
- W4384157473 date "2023-08-01" @default.
- W4384157473 modified "2023-09-26" @default.
- W4384157473 title "Palladium-catalyzed ring-closing reaction of enynols with aminals via methylene transfer and C–N bond activation" @default.
- W4384157473 cites W1968264086 @default.
- W4384157473 cites W1968593669 @default.
- W4384157473 cites W1972483674 @default.
- W4384157473 cites W1973741554 @default.
- W4384157473 cites W1977636377 @default.
- W4384157473 cites W1978263407 @default.
- W4384157473 cites W1988034621 @default.
- W4384157473 cites W1989035218 @default.
- W4384157473 cites W1990566982 @default.
- W4384157473 cites W1991421016 @default.
- W4384157473 cites W1991706263 @default.
- W4384157473 cites W2000157693 @default.
- W4384157473 cites W2003006252 @default.
- W4384157473 cites W2004483777 @default.
- W4384157473 cites W2012373379 @default.
- W4384157473 cites W2014055736 @default.
- W4384157473 cites W2040963054 @default.
- W4384157473 cites W2058785536 @default.
- W4384157473 cites W2062960055 @default.
- W4384157473 cites W2070884641 @default.
- W4384157473 cites W2078102764 @default.
- W4384157473 cites W2090260187 @default.
- W4384157473 cites W2105842291 @default.
- W4384157473 cites W2128951776 @default.
- W4384157473 cites W2139591189 @default.
- W4384157473 cites W2140889506 @default.
- W4384157473 cites W2152267227 @default.
- W4384157473 cites W2153829659 @default.
- W4384157473 cites W2154397058 @default.
- W4384157473 cites W2162265988 @default.
- W4384157473 cites W2167327884 @default.
- W4384157473 cites W2234167111 @default.
- W4384157473 cites W2275066646 @default.
- W4384157473 cites W2310934415 @default.
- W4384157473 cites W2313052053 @default.
- W4384157473 cites W2319679993 @default.
- W4384157473 cites W2333506656 @default.
- W4384157473 cites W2334495070 @default.
- W4384157473 cites W2341526708 @default.
- W4384157473 cites W2432917841 @default.
- W4384157473 cites W2436754680 @default.
- W4384157473 cites W2468981195 @default.
- W4384157473 cites W2542419410 @default.
- W4384157473 cites W2565914895 @default.
- W4384157473 cites W2622502211 @default.
- W4384157473 cites W2626170714 @default.
- W4384157473 cites W2755092411 @default.
- W4384157473 cites W2884212343 @default.
- W4384157473 cites W2905429823 @default.
- W4384157473 cites W2910249051 @default.
- W4384157473 cites W2921502723 @default.
- W4384157473 cites W2949233753 @default.
- W4384157473 cites W2950132667 @default.
- W4384157473 cites W2952987318 @default.
- W4384157473 cites W2989600854 @default.
- W4384157473 cites W3001416510 @default.
- W4384157473 cites W3012966632 @default.
- W4384157473 cites W3017685932 @default.
- W4384157473 cites W3036574326 @default.
- W4384157473 cites W3080755859 @default.
- W4384157473 cites W3088742259 @default.
- W4384157473 cites W3092199769 @default.
- W4384157473 cites W3093134328 @default.
- W4384157473 cites W3095264139 @default.
- W4384157473 cites W3143751217 @default.
- W4384157473 cites W3162342352 @default.
- W4384157473 cites W3163473284 @default.
- W4384157473 cites W3164628794 @default.
- W4384157473 cites W3195932503 @default.
- W4384157473 cites W4237245744 @default.
- W4384157473 cites W4255764754 @default.
- W4384157473 cites W4295018376 @default.
- W4384157473 cites W4361808068 @default.
- W4384157473 doi "https://doi.org/10.1016/j.tchem.2023.100042" @default.
- W4384157473 hasPublicationYear "2023" @default.
- W4384157473 type Work @default.
- W4384157473 citedByCount "0" @default.
- W4384157473 crossrefType "journal-article" @default.
- W4384157473 hasAuthorship W4384157473A5014364892 @default.
- W4384157473 hasAuthorship W4384157473A5063833862 @default.
- W4384157473 hasAuthorship W4384157473A5067490406 @default.
- W4384157473 hasBestOaLocation W43841574731 @default.
- W4384157473 hasConcept C131779359 @default.
- W4384157473 hasConcept C155647269 @default.
- W4384157473 hasConcept C161790260 @default.
- W4384157473 hasConcept C178790620 @default.
- W4384157473 hasConcept C185592680 @default.
- W4384157473 hasConcept C21951064 @default.
- W4384157473 hasConcept C2777454769 @default.
- W4384157473 hasConcept C40875361 @default.