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• W4384211027 endingPage "10804" @default.
• W4384211027 startingPage "10795" @default.
• W4384211027 abstract "Thiol-containing biomolecules, such as cysteine and glutathione, play essential roles in regulating the polarity and reactivity of the systems. Among functional MOFs, thiol MOFs, a subclass with a thiol group-containing ligand, are relatively less explored due to their synthetic challenges and stability and storage issues. Despite these drawbacks, they have many advantages due to the electronically soft thiol groups with strong reactivity and affinity toward soft metal ions. Herein, we have taken advantage of the affinity between thiol groups and a soft metal (Ag) by functionalizing a thiol MOF with Ag ions and finally synthesizing a silver nanoparticle-functionalized heterogeneous catalyst (Ag@Zr-DMBD). The Zr,Ag centre of the thiol MOF catalyst acts as an active centre and synergistically binds with the electron-rich oxygen atom of a terminal epoxide for efficient CO2 fixation to the corresponding cyclic carbonates under atmospheric CO2 pressure in 8 h. Finally, a rationalized reaction mechanism is proposed based on literature reports and current results. This work presents a viable strategy for using thiol MOFs as heterogeneous catalysts for CO2 fixation under mild conditions." @default.
• W4384211027 created "2023-07-14" @default.
• W4384211027 creator A5028737967 @default.
• W4384211027 creator A5056396186 @default.
• W4384211027 date "2023-01-01" @default.
• W4384211027 modified "2023-10-16" @default.
• W4384211027 title "A Thiol-Containing Zirconium MOF Functionalized with Silver Nanoparticles for Synergistic CO₂Cycloaddition Reactions" @default.
• W4384211027 cites W1677747913 @default.
• W4384211027 cites W1835629181 @default.
• W4384211027 cites W1837570539 @default.
• W4384211027 cites W1986238480 @default.
• W4384211027 cites W1994442356 @default.
• W4384211027 cites W1998408986 @default.
• W4384211027 cites W1999918445 @default.
• W4384211027 cites W2002799357 @default.
• W4384211027 cites W2004550299 @default.
• W4384211027 cites W2007438218 @default.
• W4384211027 cites W2014659473 @default.
• W4384211027 cites W2017643972 @default.
• W4384211027 cites W2030646050 @default.
• W4384211027 cites W2040252660 @default.
• W4384211027 cites W2044369290 @default.
• W4384211027 cites W2051808592 @default.
• W4384211027 cites W2056127514 @default.
• W4384211027 cites W2058950832 @default.
• W4384211027 cites W2059618910 @default.
• W4384211027 cites W2068377669 @default.
• W4384211027 cites W2073841855 @default.
• W4384211027 cites W2080864001 @default.
• W4384211027 cites W2106528615 @default.
• W4384211027 cites W2112307556 @default.
• W4384211027 cites W2125053394 @default.
• W4384211027 cites W2138511470 @default.
• W4384211027 cites W2141939342 @default.
• W4384211027 cites W2155305805 @default.
• W4384211027 cites W2246944211 @default.
• W4384211027 cites W2300630085 @default.
• W4384211027 cites W2313363323 @default.
• W4384211027 cites W2319195884 @default.
• W4384211027 cites W2495460086 @default.
• W4384211027 cites W2515435071 @default.
• W4384211027 cites W2554572011 @default.
• W4384211027 cites W2560170949 @default.
• W4384211027 cites W2593757145 @default.
• W4384211027 cites W2760136293 @default.
• W4384211027 cites W2779937803 @default.
• W4384211027 cites W2797529406 @default.
• W4384211027 cites W2804085526 @default.
• W4384211027 cites W2807834141 @default.
• W4384211027 cites W2810231302 @default.
• W4384211027 cites W2897248872 @default.
• W4384211027 cites W2898388174 @default.
• W4384211027 cites W2907359021 @default.
• W4384211027 cites W2912674222 @default.
• W4384211027 cites W2919329083 @default.
• W4384211027 cites W2939041730 @default.
• W4384211027 cites W2947645635 @default.
• W4384211027 cites W2951027422 @default.
• W4384211027 cites W2972753203 @default.
• W4384211027 cites W2974006352 @default.
• W4384211027 cites W2975144471 @default.
• W4384211027 cites W2992608489 @default.
• W4384211027 cites W3001657240 @default.
• W4384211027 cites W3017173906 @default.
• W4384211027 cites W3023124676 @default.
• W4384211027 cites W3040385785 @default.
• W4384211027 cites W3047156543 @default.
• W4384211027 cites W3087025164 @default.
• W4384211027 cites W3092219233 @default.
• W4384211027 cites W3103218042 @default.
• W4384211027 cites W3112651145 @default.
• W4384211027 cites W3116487054 @default.
• W4384211027 cites W3127881081 @default.
• W4384211027 cites W3128645345 @default.
• W4384211027 cites W3129306524 @default.
• W4384211027 cites W3144649532 @default.
• W4384211027 cites W3155859358 @default.
• W4384211027 cites W3155880190 @default.
• W4384211027 cites W3157832699 @default.
• W4384211027 cites W3158258812 @default.
• W4384211027 cites W3161084314 @default.
• W4384211027 cites W3167180297 @default.
• W4384211027 cites W3174173253 @default.
• W4384211027 cites W3201516809 @default.
• W4384211027 cites W3201870778 @default.
• W4384211027 cites W3202489885 @default.
• W4384211027 cites W4200222615 @default.
• W4384211027 cites W4200242682 @default.
• W4384211027 cites W4200588282 @default.
• W4384211027 cites W4210905717 @default.
• W4384211027 cites W4212822075 @default.
• W4384211027 cites W4220673437 @default.
• W4384211027 cites W4226441948 @default.
• W4384211027 cites W4234136656 @default.
• W4384211027 cites W4244777415 @default.
• W4384211027 cites W4283326792 @default.
• W4384211027 cites W4286664750 @default.
• W4384211027 cites W4292283975 @default.

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