Matches in SemOpenAlex for { <https://semopenalex.org/work/W4384283642> ?p ?o ?g. }
- W4384283642 endingPage "107125" @default.
- W4384283642 startingPage "107125" @default.
- W4384283642 abstract "A thermodynamic model has been developed for calculating speciation and phase equilibria in aqueous solutions of rare earth elements (REEs) with hydroxide, acetate, citrate, and oxalate anions. The computational framework is based on the Mixed-Solvent Electrolyte (MSE) framework, which has been previously used to establish a systematic treatment of binary and multicomponent systems containing REE sulfates and chlorides up to solid-liquid saturation at temperatures up to 300 °C. The model has been parametrized by performing a multi-property analysis of critically evaluated speciation and solubility data. For rare earth hydroxides, a comprehensive model has been developed for fourteen REEs (i.e., for yttrium and all lanthanides except promethium). The effect of the crystallinity of rare earth hydroxides on their solubility has been analyzed. Model parameters have been determined for two limiting cases, i.e., for crystalline and amorphous hydroxides, while recognizing that the hydroxides may span a range of degrees of crystallinity. For the organic ligands, the model has been established for neodymium with additional analysis for other selected REEs. The model accurately reproduces the effects of pH, temperature, and complexation with organic ligands on the behavior of rare earth elements in aqueous solutions. When coupled with previously developed models for inorganic rare earth salts, it provides a thermodynamic tool for the design and optimization of separation processes for the production and recycling of REEs and for predicting the properties of REEs in geological and biological settings." @default.
- W4384283642 created "2023-07-15" @default.
- W4384283642 creator A5016223283 @default.
- W4384283642 creator A5046194853 @default.
- W4384283642 creator A5066275207 @default.
- W4384283642 creator A5066415307 @default.
- W4384283642 creator A5074885018 @default.
- W4384283642 creator A5081185980 @default.
- W4384283642 date "2023-11-01" @default.
- W4384283642 modified "2023-10-12" @default.
- W4384283642 title "Modeling phase equilibria and speciation in aqueous solutions of rare earth elements with hydroxide and organic ligands" @default.
- W4384283642 cites W1540744601 @default.
- W4384283642 cites W1597706934 @default.
- W4384283642 cites W1605666009 @default.
- W4384283642 cites W1800856591 @default.
- W4384283642 cites W1802479731 @default.
- W4384283642 cites W1963659954 @default.
- W4384283642 cites W1965217560 @default.
- W4384283642 cites W1966726278 @default.
- W4384283642 cites W1967634687 @default.
- W4384283642 cites W1968081595 @default.
- W4384283642 cites W1974579410 @default.
- W4384283642 cites W1976323485 @default.
- W4384283642 cites W1979299374 @default.
- W4384283642 cites W1980580706 @default.
- W4384283642 cites W1981714961 @default.
- W4384283642 cites W1983388707 @default.
- W4384283642 cites W1983545026 @default.
- W4384283642 cites W1985302835 @default.
- W4384283642 cites W1987545857 @default.
- W4384283642 cites W1987660750 @default.
- W4384283642 cites W1989842829 @default.
- W4384283642 cites W1990159026 @default.
- W4384283642 cites W1990340486 @default.
- W4384283642 cites W1990392523 @default.
- W4384283642 cites W1992163933 @default.
- W4384283642 cites W1997953504 @default.
- W4384283642 cites W1999848155 @default.
- W4384283642 cites W2003685350 @default.
- W4384283642 cites W2009659619 @default.
- W4384283642 cites W2010108805 @default.
- W4384283642 cites W2013488233 @default.
- W4384283642 cites W2014365296 @default.
- W4384283642 cites W2016728025 @default.
- W4384283642 cites W2017717632 @default.
- W4384283642 cites W2020598143 @default.
- W4384283642 cites W2020779340 @default.
- W4384283642 cites W2021657839 @default.
- W4384283642 cites W2022176300 @default.
- W4384283642 cites W2023912267 @default.
- W4384283642 cites W2025873708 @default.
- W4384283642 cites W2026798197 @default.
- W4384283642 cites W2031057485 @default.
- W4384283642 cites W2033324610 @default.
- W4384283642 cites W2037569486 @default.
- W4384283642 cites W2041321476 @default.
- W4384283642 cites W2047372568 @default.
- W4384283642 cites W2048555478 @default.
- W4384283642 cites W2051386653 @default.
- W4384283642 cites W2061388118 @default.
- W4384283642 cites W2064671284 @default.
- W4384283642 cites W2066527077 @default.
- W4384283642 cites W2068240095 @default.
- W4384283642 cites W2069227330 @default.
- W4384283642 cites W2071214494 @default.
- W4384283642 cites W2073700851 @default.
- W4384283642 cites W2076503727 @default.
- W4384283642 cites W2077465677 @default.
- W4384283642 cites W2077871720 @default.
- W4384283642 cites W2080062032 @default.
- W4384283642 cites W2080631826 @default.
- W4384283642 cites W2081258920 @default.
- W4384283642 cites W2083273324 @default.
- W4384283642 cites W2089311670 @default.
- W4384283642 cites W2092027325 @default.
- W4384283642 cites W2094818470 @default.
- W4384283642 cites W2102305759 @default.
- W4384283642 cites W2104045002 @default.
- W4384283642 cites W2111473359 @default.
- W4384283642 cites W2116073420 @default.
- W4384283642 cites W2134969742 @default.
- W4384283642 cites W2139084683 @default.
- W4384283642 cites W2139906905 @default.
- W4384283642 cites W2154453374 @default.
- W4384283642 cites W2159409075 @default.
- W4384283642 cites W2159544707 @default.
- W4384283642 cites W2167590372 @default.
- W4384283642 cites W2169445761 @default.
- W4384283642 cites W2185127701 @default.
- W4384283642 cites W2278228533 @default.
- W4384283642 cites W2283207019 @default.
- W4384283642 cites W2313802180 @default.
- W4384283642 cites W2314009151 @default.
- W4384283642 cites W2316901692 @default.
- W4384283642 cites W2319950062 @default.
- W4384283642 cites W2320521015 @default.
- W4384283642 cites W2332430988 @default.
- W4384283642 cites W2497190641 @default.