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- W4384296897 abstract "The asymmetric α-allylation of α-aryl-substituted 2-acetyl imidazoles synergistically catalyzed by Ni/Pd catalysts has been developed. In this process, the nickel-bisoxazoline complex activates the enolate of an acetyl imidazole, which then reacts with a π-allyl palladium electrophile generated from an allyl alcohol derivative by a palladium-based catalyst. A broad scope of substrates was suitable for this reaction. The utility of this method was demonstrated by a gram-scale reaction and subsequent elaboration of the allylation products." @default.
- W4384296897 created "2023-07-15" @default.
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- W4384296897 date "2023-07-14" @default.
- W4384296897 modified "2023-09-27" @default.
- W4384296897 title "Synergistic Ni/Pd Catalysis for Asymmetric Allylic Alkylation of 2-Acyl Imidazoles" @default.
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- W4384296897 doi "https://doi.org/10.1021/acs.orglett.3c01726" @default.
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