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- W4384297773 abstract "An iridium-catalyzed intramolecular asymmetric allylic etherification of pyrimidinemethanols is described. In the presence of chiral-bridged biphenyl phosphoramidite ligand L3 and triethylborane, this process provided a class of novel pyrimidine-fused oxazepanes in up to 99% yield with 99.5% enantiomeric excess. The work addresses the challenge of insufficient nucleophilicity of aliphatic alcohols for allyl substitution and indicates the vital value of chiral-bridged biphenyl phosphoramidites. Various multifunctionalized transformations of the products further demonstrate the robust synthetic utility of this methodology." @default.
- W4384297773 created "2023-07-15" @default.
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- W4384297773 date "2023-07-14" @default.
- W4384297773 modified "2023-10-18" @default.
- W4384297773 title "Iridium-Catalyzed Intramolecular Asymmetric Allylic Etherification of Pyrimidinemethanols: Enantioselective Construction of Multifunctionalized Pyrimidine-Fused Oxazepines" @default.
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- W4384297773 doi "https://doi.org/10.1021/acs.orglett.3c01962" @default.
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