Matches in SemOpenAlex for { <https://semopenalex.org/work/W4384337910> ?p ?o ?g. }
- W4384337910 endingPage "11848" @default.
- W4384337910 startingPage "11837" @default.
- W4384337910 abstract "The design and development of electromagnetic and magnetoelectric materials with enhanced properties and performance are desirable for numerous technologies, which are based on integrated electromagnetic materials and components. Nevertheless, engineering the crystalline materials with multi-complex chemistry and multiple cations is challenging. In this context, herein, we report on the effect of rare-earth (RE) cations, namely, Dy3+ and Tb3+, co-substituted into the Co-Ni-mixed ferrite materials for applications in stress/torque sensors. The RE-cations that co-substituted Co-Ni-ferrite materials with a composition of Ni0.8Co0.2Fe2-x(Dy1-yTby)xO4 (x = 0-0.1, y = 0.3; NCFDT) were prepared by the high-temperature solid-state chemical reaction method. The effect of variable composition (x) on the structure, morphology, chemical bonding, and magnetic properties of NCFDT materials is investigated in detail, and the structure-property optimization enabled realizing magnetostrictive NCFDT for sensor applications. X-ray diffraction analysis coupled with Rietveld refinement confirms the face-centered cubic crystal structure. Chemical bonding analysis made using Raman spectroscopic and Fourier transform infrared spectroscopic measurements validates the active modes corresponding to the spinel ferrite structure. The effect of Dy3+ and Tb3+ substitution is primarily seen in the grain size (range of 5-15 μm), as evident from the scanning electron microscopy patterns. Energy-dispersive spectroscopy confirms the presence of all constituent elements with expected composition and without any impurities. The magnetic property measurements indicate that the remnant magnetization (Mr) increases from 0.06 to 0.17 μB/f.u. with the rare-earth (Dy and Tb) substitution and has achieved the maximum squareness ratio (Mr/Ms) = 0.097 at x = 0.10. To validate their application potential in magneto-mechanical sensors, we have measured the magnetostriction coefficients (λ11 and λ12), which demonstrate high values of λ11 = -92 ppm (along the parallel direction) and λ12 = 66 ppm (along the perpendicular direction) for NCFDT with x = 0.05 at H = 7000 Oe. In addition, the maximum value of strain sensitivity is observed, particularly dλ11dH = -0.764 nm/A whereas dλ12dH = 0.361 nm/A. The correlation between strain sensitivity (dλ/dH) and susceptibility (dM/dH), as derived from magnetostriction and magnetization measurements, respectively, is established. The outcomes of this study indicate that Ni-Co-ferrites with Dy3+ and Tb3+ substitution are suitable for stress/torque sensors. These NCFDT ferrites may also be useful as a necessary constitutive phase for the manufacture of magnetoelectric composite materials, making them appropriate for magnetic field sensors and energy harvesting applications." @default.
- W4384337910 created "2023-07-15" @default.
- W4384337910 creator A5006428020 @default.
- W4384337910 creator A5051999347 @default.
- W4384337910 creator A5073590808 @default.
- W4384337910 creator A5075272131 @default.
- W4384337910 creator A5090075127 @default.
- W4384337910 date "2023-07-14" @default.
- W4384337910 modified "2023-10-14" @default.
- W4384337910 title "Effect of Dy<sup>3+</sup> and Tb<sup>3+</sup> Rare-Earth Cation Co-Substitution on the Structure, Magnetic, and Magnetostrictive Properties of Ni-Co-Ferrites" @default.
- W4384337910 cites W1499468219 @default.
- W4384337910 cites W1525781344 @default.
- W4384337910 cites W1969967302 @default.
- W4384337910 cites W1971965137 @default.
- W4384337910 cites W1975398332 @default.
- W4384337910 cites W1981993001 @default.
- W4384337910 cites W1985311791 @default.
- W4384337910 cites W1987375210 @default.
- W4384337910 cites W1991993149 @default.
- W4384337910 cites W1996206996 @default.
- W4384337910 cites W1997083639 @default.
- W4384337910 cites W1999364501 @default.
- W4384337910 cites W2003349574 @default.
- W4384337910 cites W2005226015 @default.
- W4384337910 cites W2008763125 @default.
- W4384337910 cites W2009122291 @default.
- W4384337910 cites W2010002582 @default.
- W4384337910 cites W2011940302 @default.
- W4384337910 cites W2012351834 @default.
- W4384337910 cites W2022201529 @default.
- W4384337910 cites W2025664687 @default.
- W4384337910 cites W2027541111 @default.
- W4384337910 cites W2032806024 @default.
- W4384337910 cites W2036022417 @default.
- W4384337910 cites W2036111795 @default.
- W4384337910 cites W2036231334 @default.
- W4384337910 cites W2038348354 @default.
- W4384337910 cites W2041683822 @default.
- W4384337910 cites W2055980671 @default.
- W4384337910 cites W2058101211 @default.
- W4384337910 cites W2058708170 @default.
- W4384337910 cites W2063563908 @default.
- W4384337910 cites W2064217604 @default.
- W4384337910 cites W2067282930 @default.
- W4384337910 cites W2067388614 @default.
- W4384337910 cites W2072942832 @default.
- W4384337910 cites W2075272898 @default.
- W4384337910 cites W2075316186 @default.
- W4384337910 cites W2087902362 @default.
- W4384337910 cites W2091172758 @default.
- W4384337910 cites W2093615704 @default.
- W4384337910 cites W2093785226 @default.
- W4384337910 cites W2094244284 @default.
- W4384337910 cites W2108997930 @default.
- W4384337910 cites W2120483229 @default.
- W4384337910 cites W2139573832 @default.
- W4384337910 cites W2330796056 @default.
- W4384337910 cites W2601220496 @default.
- W4384337910 cites W2727897178 @default.
- W4384337910 cites W2766351448 @default.
- W4384337910 cites W2769793540 @default.
- W4384337910 cites W2800177758 @default.
- W4384337910 cites W2801101910 @default.
- W4384337910 cites W2801717575 @default.
- W4384337910 cites W2896782029 @default.
- W4384337910 cites W2917623759 @default.
- W4384337910 cites W2919756633 @default.
- W4384337910 cites W2949195806 @default.
- W4384337910 cites W2982544820 @default.
- W4384337910 cites W2985611103 @default.
- W4384337910 cites W2990493827 @default.
- W4384337910 cites W3036833822 @default.
- W4384337910 cites W3036883353 @default.
- W4384337910 cites W3087199735 @default.
- W4384337910 cites W3099528638 @default.
- W4384337910 cites W3099623251 @default.
- W4384337910 cites W3103454141 @default.
- W4384337910 cites W3114476305 @default.
- W4384337910 cites W3124628817 @default.
- W4384337910 cites W3131541353 @default.
- W4384337910 cites W3160953465 @default.
- W4384337910 cites W3164453106 @default.
- W4384337910 cites W3192387222 @default.
- W4384337910 cites W3193677677 @default.
- W4384337910 cites W3209730121 @default.
- W4384337910 cites W4210549793 @default.
- W4384337910 cites W4230748214 @default.
- W4384337910 cites W4283580996 @default.
- W4384337910 cites W4296617529 @default.
- W4384337910 cites W4309682146 @default.
- W4384337910 cites W4316276760 @default.
- W4384337910 cites W4321381575 @default.
- W4384337910 doi "https://doi.org/10.1021/acs.inorgchem.3c01117" @default.
- W4384337910 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37450403" @default.
- W4384337910 hasPublicationYear "2023" @default.
- W4384337910 type Work @default.
- W4384337910 citedByCount "0" @default.
- W4384337910 crossrefType "journal-article" @default.