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• W4384339619 abstract "Palladium-catalyzed activation of C-C bonds in organic molecules is a powerful tool for the synthesis of value-added compounds. 5-Hydroxymethylfurfural (HMF) derivatives are a promising class of biomass-derived chemicals that have received considerable attention due to their potential applications in the synthesis of biologically active molecules and materials. However, the selective activation of unstrained C-C bonds is a challenging task, mainly due to their relatively high bond dissociation energies. Herein, we report a palladium-catalyzed method for the efficient C-C bond activation of HMF derivatives, enabling their arylation with iodobenzenes. Mechanistic studies, including reaction-profile analysis, competition experiments and head-space IR spectroscopy suggest a decarboxylative mechanism." @default.
• W4384339619 created "2023-07-15" @default.
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• W4384339619 date "2023-09-13" @default.
• W4384339619 modified "2023-10-18" @default.
• W4384339619 title "Pd‐Catalyzed Activation of Carbon‐Carbon Bonds in Hydroxymethylfurfural Derivatives" @default.
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• W4384339619 doi "https://doi.org/10.1002/chem.202302038" @default.
• W4384339619 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37449730" @default.
• W4384339619 hasPublicationYear "2023" @default.
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