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• W4384340043 abstract "The crystal structure of K6[Zn(CO3)4], hexa-potassium tetra-carbonato-zincate(II), comprises four unique potassium cations (two located on a general position, and two on the twofold rotation axis of the space group C2/c) and a [Zn(CO3)4]6- anion. The ZnII atom of the latter is located on the twofold rotation axis and is surrounded in a slightly distorted tetra-hedral manner by two pairs of monodentately binding carbonate groups, with Zn-O distances of 1.9554 (18) and 1.9839 (18) Å. Both carbonate groups exhibit a slight deviation from planarity, with the C atom being shifted by 0.008 (2) and 0.006 (3) Å, respectively, from the plane of the three O atoms. The coordination numbers of the potassium cations range from 6 to 8, using a threshold of 3.0 Å for K-O bonding inter-actions being significant. In the crystal structure, [KOx] polyhedra and [Zn(CO3)4]6- groups share O atoms to build up the framework structure." @default.
• W4384340043 created "2023-07-15" @default.
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• W4384340043 creator A5058070501 @default.
• W4384340043 date "2023-07-14" @default.
• W4384340043 modified "2023-09-25" @default.
• W4384340043 title "Crystal structure of K₆[Zn(CO₃)₄]" @default.
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• W4384340043 doi "https://doi.org/10.1107/s2056989023006072" @default.
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